Calculating equilibrium constants Keq

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Discussion Overview

The discussion revolves around calculating the concentration of chlorine gas ([Cl2]) in a chemical equilibrium involving iron and chlorine, specifically the reaction 2Fe(s) + 3Cl2(g) ⇔ 2FeCl3(s). Participants are addressing a homework problem that includes a given equilibrium constant (Keq) and are exploring the necessary information to determine the concentration of Cl2.

Discussion Character

  • Homework-related

Main Points Raised

  • One participant expresses confusion about needing more information to solve for [Cl2], given the provided Keq value.
  • Another participant questions the purpose of the calculation since Keq is already provided, implying that the participant may not understand the goal of the problem.
  • A third participant clarifies that calculating "moles of Cl2" is not feasible without additional information, such as the volume of the container, which is necessary to relate moles to concentration.
  • There is a suggestion that the equilibrium pressure of the gas is known at a given temperature, but without volume, further calculations cannot be made.

Areas of Agreement / Disagreement

Participants generally agree that there is insufficient information to calculate the concentration of Cl2, but there is some confusion regarding the goal of the problem and how to approach it.

Contextual Notes

The discussion highlights limitations in the information provided, such as the absence of volume for the gas and the need for clarity on the specific calculations being sought.

Dave1212
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Homework Statement


2Fe(s) + 3Cl2(g) ⇔ 2FeCl3(s)[/B]
Keq = 53.25 [CL2(g)] = ?M
Answer = [0.2658M]

Homework Equations


Keq = (cC)(dD)/(aA)(bB)

The Attempt at a Solution



Keq = [Cl2]3

53.25 = (Cl2)3

I’m confused because I feel like I need more to work with in this question. It seems like I need another number and I don’t know where to start on it.

Thanks in advance!
 
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What are you trying to calculate? Thread subject says "calculating equilibrium constants" yet Keq is given.
 
Borek said:
What are you trying to calculate? Thread subject says "calculating equilibrium constants" yet Keq is given.

Trying to calculate the Moles for Cl2
 
Not enough information. Can you quote entire question?
 
You can't calculate "moles of Cl2". You have two solids and a gas in equilibrium. At any temperature, there is an equilibrium pressure for the gas. That's all you know, unless you have a volume for the container, and can calculate the total amount of gas.
 

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