Calculating Molarity for a Diluted Ethanol Solution - Quick Dilution Question

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Discussion Overview

The discussion revolves around calculating the molarity of a diluted ethanol solution in a laboratory context. Participants explore the correct approach to determine molarity based on the number of moles of ethanol and the total volume of the solution after dilution.

Discussion Character

  • Homework-related
  • Mathematical reasoning
  • Technical explanation

Main Points Raised

  • One participant states that to find molarity, the number of moles (1.72x10^-4) should be divided by the volume of the solution, questioning whether to use 0.01 liters or 0.1 liters.
  • Another participant clarifies that the correct volume for molarity calculation should be 0.1 liters, but notes that the total volume may not be exactly 100 mL due to dilution details.
  • A later post provides context about the reaction involving dichromate ion and ethanol, indicating that the moles of ethanol are related to the oxidation process in the lab.
  • One participant suggests converting grams to mL using ethanol's density (0.789 g/mL) to find the volume of ethanol oxidized.
  • Another participant confirms the calculation of the volume of ethanol oxidized, relating it back to the dilution and the proportion of the sample taken for analysis.

Areas of Agreement / Disagreement

Participants express uncertainty about the exact volume to use for calculating molarity and whether the dilution details significantly affect the outcome. There is no consensus on the best approach to resolve these uncertainties.

Contextual Notes

Participants mention potential discrepancies in the total volume after dilution and the implications of using different volumes for calculations. The discussion does not resolve these mathematical uncertainties.

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Homework Statement


The mols of ethanol is 1.72x10^-4. I am trying to find its volume. However, I am confused on what the molarity of this solution is. (Molarity here is in mol/L)

(the 10mL sample contained 1.72x10^-4 mols of ethanol, but it was diluted in 90 mL water)

The lab said:
"Dilute the 10.0 mL ethanol sample as such: (10.0 mL ethanol in 90.0 mL of distilled water, for a total of 100.0 mL)."

The Attempt at a Solution



The mols of ethanol is 1.72x10^-4. Do I divide this figure by .01 liters? Or do I do it by .1? I think it's one or the other but either way I need this calculation perfect or the rest of the lab is moot!
 
Last edited:
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If you want to find the molarity, you divide the number of moles by the volume (here: .1 liter).

I don't see which volume you want to find.

10ml ethanol plus 90ml distilled water won't give exactly 100ml, but that's probably a negligible detail.
 
Oops, sorry! My original post was a bit unclear.

The original dilution scheme was 10 mL of the ethanol in 90mL water [I think my teacher isn't really concerned with the negligible detail(s)]

1.72x10^-4 mols of ethanol is the mols of ethanol oxidized by dichromate ion in my lab. I am trying to find the volume of those mols. The procedure included preparing a solution by adding 10 mL ethanol into 90 mL of water. We shook it up and added into a separate flask 1 mL of that solution and 21 mL of 0.01M dichromate in 5M H2SO4.

Here's the reaction if it is relevant:
2 Cr2O72− + 16 H+ + 3 C2H5OH → 4 Cr3+ + 11 H2O + 3 CH3COOH

Hopefully that clears things up! For such a simple dilution question I can't believe I'm having trouble with it, of all things to be troubled with in this lab.
 
how silly. I think I just had to convert the grams to mL using ethanol's density - (0.789g/mL).

Resulting figure would be of the 10 mL ethanol originally put in, 0.01 mL was oxidized.

7.92x10^-3 g ethanol X (1 mL/0.789g) = 0.0100mL

(7.92x10^-3 g of ethanol = 1.72x10^-4 mols of ethanol )
 
Ritzycat said:
Resulting figure would be of the 10 mL ethanol originally put in, 0.01 mL was oxidized.

You took 1 mL out of 100 mL of the diluted solution, so 1/100th of the original sample. If 0.01 mL is 1/100th of 10 mL, then you got it right.
 

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