Calculating pH and Ionization of Aspirin Solutions

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Discussion Overview

The discussion revolves around calculating the pH and ionization of aspirin solutions, addressing both theoretical and practical aspects of weak acids. Participants explore various calculations related to pH, percent ionization, and the effects of adding hydrochloric acid to the solution.

Discussion Character

  • Homework-related
  • Mathematical reasoning
  • Conceptual clarification

Main Points Raised

  • Post 1 presents a series of calculations regarding the pH of a 0.2M aspirin solution, the percent ionization, and the effects of adding hydrochloric acid.
  • Post 2 questions the interpretation of Ka and its relation to hydrogen ion concentration, suggesting a calculation for pH based on Ka.
  • Post 4 outlines a step-by-step approach to finding the hydrogen ion concentration using the formula [H+] = √(Ka * c) and discusses the common ion effect due to the addition of hydrochloric acid.

Areas of Agreement / Disagreement

Participants express differing views on the interpretation of aspirin's acidity and the calculations involved. There is no consensus on the correct approach to calculating pH and percent ionization, as well as the implications of adding hydrochloric acid.

Contextual Notes

Some assumptions regarding the behavior of weak acids and the impact of added ions remain unaddressed. The discussion does not resolve the mathematical steps or the definitions of terms used.

Who May Find This Useful

Students studying chemistry, particularly those focused on acid-base equilibria and calculations related to weak acids.

sci0x
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Question: Aspirin is a weak acid.

(a) Calculate pH of 0.2M solution of aspirin at 25 degrees celsius (Ka = 3.0 x 10^-4 at 25 degrees celsius).

(b) Determine the percent ionisation

(c) Explain qualitatively the effect of adding 0.01M hydrochloric acid to the aspirin solution.

(d) Calculate the pH of the resulting solution

(e) Determine the percent ionisation of the aspirin under these conditions
 
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hmmm
well formula goes.. pH=-log[H+]
am not sure what about aspirine...i am is Ka also meant as concentration of H+ ??
if yes ...then

pH=-log[H+]
pH=-log(3.0 x 10^-4)=3.5228

and it is acid...but wouldn't say that weak
 
Sci0x : Please read the forum guidelines for getting help with schoolwork. See my signature.
 
here is the most effective way with which u must proceed---

1) the conc is given as .2 M and ka is given so find the [tex]H^+[/tex] conc using the formula [tex][H^+] = \sqrt{K_a * c}[/tex]
2) percentage ionisation is given by the formula [tex]\sqrt{\frac{k_a}{c}}[/tex]
3)Explain common ion effect
4) due to addition of hydrochloric acid the conc of H+ will now be 0.01 + the conc of H+ u got in the 1st question
5) repeate the 2 question but now with the new conc of H+ note use formula [tex]\frac{[H^+]}{c}[/tex]
 

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