Calculating pH of Limestone Quarry Water | H2CO3 pk1=6.37, pk2=10.32

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In summary, the pH of water in a limestone quarry containing CaCO3 can be found by using the equations pH=pKa + log [conjugate base]/[acid] and Kw=10^-14. The pKa values for H2CO3 are given as 6.37 and 10.32. By calculating the concentration of OH- and using the formula pH=14-log[OH-], we can determine the pH to be approximately 12.02. However, the exact answer may vary depending on the initial concentration of carbonates and their hydrolysis. It is also worth considering the solubility product of calcium carbonate in order to obtain a more precise answer.
  • #1
coookiemonste
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Homework Statement


Find the pH of water in limestone (CaCO3) quarry.
H2CO3 pk1=6.37, pk2=10.32

Homework Equations


pH=pKa + log [conjugate base]/[acid]
Kw=10^-14

The Attempt at a Solution


CO3 2- + H2O -> HCO3- + OH-
Ka= [HCO3-][OH-]/[CO3 2-]
10^-10.32=x^2/[10^-6.37]
[OH-]=x=.01059
-log[OH-]=1.98
14-1.98=12.02
is this correct?
 
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  • #2
since its a salt, I think you can do pH= 1/2 (pKa1 + pKa2)
 
  • #3
wallace13 said:
since its a salt, I think you can do pH= 1/2 (pKa1 + pKa2)

No, that would work for solution of amphiprotic salt, here you start with fully neutralized carbonate.

A lot depends on the initial cncentration of carbonates - and this depends on the calcium carbonate solubility product. Besides, solubility will increase due to carbonates hydrolyzis, so finding an exact answer can be tricky. No idea how deep you are expected to get into it.

coookiemonste said:
Ka= [HCO3-][OH-]/[CO3 2-]
10^-10.32=x^2/[10^-6.37]

Why do you think [CO32-] = Ka1?

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FAQ: Calculating pH of Limestone Quarry Water | H2CO3 pk1=6.37, pk2=10.32

What is the pH of water in limestone?

The pH of water in limestone can vary depending on the specific composition of the limestone, but it typically ranges from 7-9.

Why does water in limestone have a higher pH?

Limestone is made up of calcium carbonate, which is a basic compound. When water comes into contact with limestone, it dissolves some of the calcium carbonate, raising the pH of the water.

How does the pH of water in limestone affect aquatic life?

The higher pH of water in limestone can be beneficial for some aquatic species, as it provides a more alkaline environment. However, it can also be harmful to certain species that require a lower pH for survival.

Can the pH of water in limestone change over time?

Yes, the pH of water in limestone can change over time due to various factors such as weathering, erosion, and changes in water flow. It can also be affected by human activities such as pollution and land use changes.

Is the pH of water in limestone safe for drinking?

In general, the pH of water in limestone is considered safe for drinking as it falls within the acceptable range of 6.5-8.5 set by the Environmental Protection Agency. However, it is always recommended to have your water tested for any potential contaminants before consuming it.

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