Calculating Wavefunction Angles in sp3 Hybridization - How to Use Integrals?

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SUMMARY

The discussion focuses on calculating the angle between wavefunctions in sp3 hybridization, specifically demonstrating that this angle is 109.5 degrees. Participants suggest using expectation values of the wavefunctions and the dot product to derive the angle. The integral evaluations are crucial for obtaining these expectation values, particularly using the position operator. Additionally, there is a side query regarding the use of [PLAIN][\IMG] tags for image display issues.

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  • Understanding of quantum mechanics and wavefunctions
  • Familiarity with sp3 hybridization concepts
  • Knowledge of expectation values and dot products in vector spaces
  • Proficiency in integral calculus for evaluating wavefunction integrals
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Zhelives
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I'm given the following matrix equation:

latex.png


I'm also given:

latex.png


We're supposed to show that the angle between any two of these wave functions is 109.5 (characteristic of sp3 hybridization). I assume I need to calculate the expectation values of x, y and z and then use the dot product, but I'm at a loss on how to evaluate the inegrals. Suggestions?

Thanks.

P.S. Forum Question: Why do the images appear as links when I use the [\IMG] tags?
 
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I have a very similar problem myself. I think you need to take the expectation value of two wavefunctions with respect to the position operator. so:
<psi_1|r|psi_1>
since the position is a vector operator you will get a vector quantity. Dot the two of them together, and I'm sure you can get it from there.

btw: how do you get LaTeX to work here?
 

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