Calculation of Percentage Composition of Hydroxyapatite in Tooth Enamel Sample

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SUMMARY

The calculation of the percentage composition of hydroxyapatite in a tooth enamel sample was successfully resolved. Initially, the user calculated an incorrect mass of hydroxyapatite due to a unit conversion error, resulting in an implausible percentage of 900.33%. After correcting the mole ratio in the calculation, the accurate mass of hydroxyapatite was determined to be 1.005678g, leading to a final percentage composition of 90.034%. This demonstrates the importance of precise unit factors in stoichiometric calculations.

PREREQUISITES
  • Understanding of stoichiometry and mole conversions
  • Familiarity with chemical equations and reactions
  • Knowledge of hydroxyapatite composition and properties
  • Basic skills in percentage calculations
NEXT STEPS
  • Study stoichiometric calculations involving multiple reactants and products
  • Learn about the properties and applications of hydroxyapatite in dental materials
  • Explore advanced topics in chemical equilibrium and reaction yields
  • Review common pitfalls in unit conversions in chemistry
USEFUL FOR

Chemistry students, educators, and professionals involved in materials science or dental research will benefit from this discussion, particularly those focusing on the composition and analysis of biological materials.

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Homework Statement


Tooth enamel is mainly hydroxyapatite,
Ca_{10}(PO_{4})_{6}(OH)_{2}
If 1.117g of tooth enamel reacts with acid to give 1.111g of Calcium Chloride, what is the percentage of hydroxyapatite in the tooth enamel sample?


Homework Equations

\

Ca_{10}(PO_{4})_{6}(OH)_{2}_{(s)} + 20HCl_{(aq)} \rightarrow 10CaCl_{2}_{(aq)} + 6H_{3}PO_{4}_{(aq)} + 2H_{2}O_{(l)}

The Attempt at a Solution



I don't know why, these questions always cause me problems. Writing out my work now...

1.111g CaCl2 * \frac{1 mol CaCl2}{110.9834g CaCl2} * \frac{1 mol Hydroxyapatite}{1 mol CaCl2} * \frac{1004.6228g Hydroxyapatite}{1 mol Hydroxyapatite} = Xg Hydroxyapatite

X = 10.05678 g Hydroxyapatite

How can that be?

That number (X) over the initial mass of the tooth enamel (1.117) should give me the percentage. But there is no way that this is correct..

\frac{10.05678}{1.117} *100\% = 900.33\%

Edit: Now that I look at it, it appears I used the wrong unit factor for converting moles... I'm working on it again.

Okay here it is:
1.111g CaCl2 * \frac{1 mol CaCl2}{110.9834g CaCl2} * \frac{1 mol Hydroxyapatite}{10 mol CaCl2} * \frac{1004.6228g Hydroxyapatite}{1 mol Hydroxyapatite} = 1.005678g Hydroxyapatite

and then:

\frac{1.005678}{1.117} * 100\% = 90.034\%

How does that look?
 
Last edited:
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