Suppose (1,1) and (8,8) are the discarded corners.
Consider the column 1. Since there are an odd number of available squares (7) , there will be a odd number of horizontal dominoes from column 1 to column 2. Being so, there will be an odd number of available squares at column 2.
Again, the same applies to the column 2, and so on, up to column 7.
So, along 7 columns, an odd number of dominoes are necessary from each column to the next.
So, the total number of horizontal dominoes is odd.S
Now, consider the rows.
Starting from row 1, with only 7 squares, the same argument applies, and there will be necessary
an odd number of vertical dominoes.
Then, the total number of dominoes (vertical + horizontal) is even although there are exactly 31 dominoes.
So, it is not possible!