Here's my highly speculative reply:
I believe that the reason why aliens or other non-terrestrial life forms would not be "robots": i.e. made of inorganic matter is because of the nature of life.
What is one of the fundamental features of "life"? One of the most fundamental features of life in terms of both empirical observation and simple conceptual analysis is that of adaptivity. I do not believe we can make sense of the concept "life" without that of adaptivity.
Now my reasoning runs as follows:
Because life must be adaptive, it must store information in some physical form. As we all know, information can be stored in both inorganic and organic matter, however one of the distinctive features of organic materials is their thermal senstivity in a relatively narrow range of temperatures. This is the blessing and curse of organic matter as a choice for life. By virtue of being easily thermally deformable it is easy to affect the functioning of an organic system by adding energy and changing the entropically favorable state, which can lead to problems with homeostasis or can lead to cancer, hence curse. This is also the blessing, because in order to adapt to the environment the organism must sense and react to its environment, which means "updating" its information content fluidly. This, I believe is the benefit of organic matter for life. It is more thermally efficient to enact a chemical reaction to slightly change the "temperature" (to the extent that we can speak of temperature) in the area and adapt to its environment.
"Robot" matter, on the other hand, is mostly intrinsic and extrinsic semiconductors characterized by, structurally, being atoms in a lattice. Lattices, of course, are often known for the strength of their bonds. So when designing computers and adding software to them, we don't want the functioning of the computer to be effected by the thermal substratum, so a strong not-easily thermally deformable material would be easier to deal with, however if you want to be able to fluidly change "your own" structure, being built of a strong lattice may not be the best choice.
So, the distinction and inter-relations between the physical dynamics and the information storage, the "hardware" and "software" is more important for "life" then for "robots".
This is of course highly speculative, and could be wrong, because there are ongoing AI resesearch porgrammes that use adaptive behavior in inorganic matter, so evidently the way I am using adaptive is not quite identical. May be more general or of a different type. Also, the reproduction process would be difficult for inorganic matter for pretty much the same reasons.