Can someone please explain overlap integrals to me?

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SUMMARY

This discussion focuses on the concept of overlap integrals within the context of quantum mechanics, specifically related to the quantum harmonic oscillator. Overlap integrals are defined as the complex conjugate of one wave function multiplied by another, analogous to the dot product of vectors. The conversation highlights that in a single harmonic oscillator scenario, eigenstates are orthogonal, resulting in overlap integrals that yield values of either 1 or 0. The mention of Franck-Condon factors indicates a more complex scenario involving multiple harmonic oscillators.

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randybryan
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I'm studying for my Quantum Mechanics course and I've understood most of it so far, until we reached the quantum harmonic oscillator. Finding the solution was no easy feat and I have to say I only had a slender grasp of the derivation, but now I'm being given questions about certain energy states that need overlap integrals. I have nothing in my nots about them. I know they're the complex conjugate of one function multiplied by another function and is equivalent to the dot product of two vectors, but where does it come from and how is it applied to the Q harmonic oscillator?
 
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randybryan said:
I'm studying for my Quantum Mechanics course and I've understood most of it so far, until we reached the quantum harmonic oscillator. Finding the solution was no easy feat and I have to say I only had a slender grasp of the derivation, but now I'm being given questions about certain energy states that need overlap integrals. I have nothing in my nots about them. I know they're the complex conjugate of one function multiplied by another function and is equivalent to the dot product of two vectors, but where does it come from and how is it applied to the Q harmonic oscillator?

Hmm ... normally one wouldn't talk about overlap integrals in the case of a single harmonic oscillator problem, right? Since all the eigenstates are orthogonal, all of the overlap integrals (which you characterized properly above, by the way), should either be 1 or 0, right?

So, are you by any chance working on a problem to calculate Franck-Condon factors? Or some other problem where you have multiple harmonic oscillators with different minima to deal with?
 

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