Can the Schrodinger equation satisfy Laplace's equation?

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SUMMARY

The discussion centers on the relationship between the time-dependent Schrödinger equation and Laplace's equation. It establishes that while the Schrödinger equation contains a Laplacian operator, rearranging it to satisfy Laplace's equation leads to non-normalizable solutions, such as spherical harmonics. The analysis reveals that in an infinite 2-D plane, solutions are not square integrable, but in a half-infinite cylindrical universe, normalizable solutions exist. Specifically, the wave function can be expressed as ψ(x,θ) = e^(2nπ/L (-x ± iy)), which satisfies the conditions for normalizability.

PREREQUISITES
  • Understanding of the time-dependent Schrödinger equation
  • Familiarity with Laplace's equation and its solutions
  • Knowledge of spherical harmonics and their properties
  • Basic concepts of Fourier transforms in quantum mechanics
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  • Explore the properties of spherical harmonics in quantum mechanics
  • Study the implications of normalizability in quantum wave functions
  • Investigate the use of Fourier transforms in solving differential equations
  • Learn about boundary conditions in quantum systems, particularly in cylindrical coordinates
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Physicists, quantum mechanics students, and researchers interested in the mathematical foundations of quantum theory and the behavior of wave functions in various geometries.

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The time-dependent Schrödinger equation is given by:

##-\frac{\hslash^{2}}{2m}\triangledown^{2}\psi+V\psi=i\hslash\frac{\partial }{\partial t}\psi##​

Obviously, there is a laplacian in the kinetic energy operator. So, I was wondering if the equation was rearranged as

##-\frac{\hslash^{2}}{2m}\triangledown^{2}\psi=i\hslash\frac{\partial }{\partial t}\psi-V\psi##​

then does there exist a wave function ## \psi## that satisfies Laplace's equation

##\triangledown^{2}\psi=0##
so that

##\triangledown^{2}\psi=i\hslash\frac{\partial }{\partial t}\psi-V\psi=0##
If so, can the solution then be a set of spherical harmonics, which is commonly found when dealing with Laplace's equation in other areas?
 
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My memory about the solution of Laplace's equation is a bit hazy but after checking wikipedia about spherical harmonics, the general solution of this equation takes the form of
$$
\psi(r,\theta,\phi) = \sum_{l=0} \sum_{m=-l}^l c_{lm} r^l Y_{lm}(\theta,\phi)
$$
which is clearly not normalizable and hence cannot serve as a square integrable solution required to be an element of Hilbert space.
 
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An attempt to solve the equation by a Fourier transform would lead to ##{\bf k}^2=0##, implying ##k_x=k_y=k_z=0##. That would correspond to a constant function, which is also not square integrable.
 
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Demystifier said:
An attempt to solve the equation by a Fourier transform would lead to ##{\bf k}^2=0##, implying ##k_x=k_y=k_z=0##. That would correspond to a constant function, which is also not square integrable.

That's true for an infinite 2-D plane. However, if your "universe" consists of a half-infinite cylinder, parametrized by x,y according to:
  • 0 \leq x \lt \infty
  • 0 \leq y \leq L
  • The point (x,y) and the point (x, y+L) are identified.
Then there are normalizable solutions of the form:

\psi(x,\theta) = e^{\frac{2n\pi}{L} (-x \pm i y)}
 
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