Can Total Alkalinity and Carbonate Concentration Determine pH?

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SUMMARY

The discussion confirms that total alkalinity and total carbonate concentration can be used to determine the pH of a solution. The formula for total alkalinity is given as Total alkalinity = [OH]- + [HCO3]- + 2 x [CO3]2- - [H]+. Participants emphasize the importance of considering other ions present in real water, which can affect alkalinity. Additionally, the impact of carbon dioxide saturation on alkalinity is highlighted as a significant factor in pH determination.

PREREQUISITES
  • Understanding of acid-base chemistry and pH concepts
  • Familiarity with chemical equilibrium and ion concentrations
  • Knowledge of carbonate chemistry and its role in alkalinity
  • Basic grasp of how carbon dioxide affects water chemistry
NEXT STEPS
  • Research the relationship between carbon dioxide saturation and alkalinity in aqueous solutions
  • Study the effects of various ions on total alkalinity and pH
  • Explore the use of titration methods to measure alkalinity and pH
  • Learn about the role of bicarbonates and carbonates in buffering systems
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Chemists, environmental scientists, and water quality analysts who are involved in water chemistry and pH regulation will benefit from this discussion.

gabriels-horn
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If given total alkalinity of a solution, and total carbonate concentration, is it possible to find the pH of that solution?

Total alkalinity = [OH]- + [HCO3]- + 2 x [CO3]2- - [H]+
 
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Well,to check I guess you could see whether or not a hyrdogen ion would react with any of those alkaline materials because after all, the strict definition of a base is a proton acceptor...
 
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gabriels-horn said:
Total alkalinity = [OH]- + [HCO3]- + 2 x [CO3]2- - [H]+

What about other things? Real water usually contains also other ions which are also included in the alkalinity.

The hint: does saturation of the solution with carbon dioxide change alkalinity?
 

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