Why Do Enthalpy and Entropy Changes Often Seem Temperature-Independent?

  • Thread starter Thread starter kasse
  • Start date Start date
  • Tags Tags
    Change Entropy
Click For Summary
The discussion centers on the assumption that enthalpy and entropy changes in reactions can be considered temperature-independent, particularly in early undergraduate chemistry. Participants question whether the enthalpy and entropy of reactants and products remain constant or if they vary with temperature, and if so, whether the rate of change is uniform across all substances. It is noted that this assumption is a simplification that does not hold true in advanced thermodynamics. Some cases may allow for a weighted value due to minimal temperature impact on enthalpy changes. The conversation emphasizes the need for deeper understanding and tools in real thermodynamic applications.
kasse
Messages
383
Reaction score
1
Why is it that the change in enthalpy and entropy of a reaction often can be assumed not to depend on temperature?
 
Physics news on Phys.org
You've been posting long enough to know that you must do your work before anyone can help you. So what are your thoughts on the matter? Are the enthalpy and entropy of reactants and products constant? If they change with temperature, is the rate of change the same for all reactants and products?
 
It is a simplification in early undergrad chemistry. When you get to real thermodynamics, you will see that this is not true, they will give you the tools then that will aid you.

Although in some cases the change in enthalphy is so small according to temperature that you can use a weighted value.
 
But why?
 

Similar threads

  • · Replies 4 ·
Replies
4
Views
2K
  • · Replies 1 ·
Replies
1
Views
2K
Replies
2
Views
2K
Replies
1
Views
2K
  • · Replies 5 ·
Replies
5
Views
2K
  • · Replies 3 ·
Replies
3
Views
3K
  • · Replies 10 ·
Replies
10
Views
3K
Replies
13
Views
4K
Replies
4
Views
2K
  • · Replies 2 ·
Replies
2
Views
2K