[Chem] Buffer solution with acetic acid

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    Acid Buffer Chem
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SUMMARY

The discussion centers on the preparation of a buffer solution using 0.30M acetic acid and 0.10M sodium acetate, followed by the addition of 100mL of 0.10M HNO3. The equilibrium reaction indicates that both CH3COO- and H+ reach a molarity of zero, leading to the conclusion that the acetic acid and sodium nitrate are the predominant species in the solution. The equilibrium constant (Ka) for acetic acid is 1.8 x 10-5, which is crucial for understanding the buffer's behavior under acidic conditions.

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  • Understanding of buffer solutions and their components
  • Knowledge of equilibrium concepts in chemistry
  • Familiarity with ICE tables for equilibrium calculations
  • Basic stoichiometry related to acid-base reactions
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Homework Statement


100mL of 0.10M HNO3 was added to a 100mL mixture containing 0.30M acetic acid and 0.10M sodium acetate.
Ka = 1.8 x 10-5


Homework Equations


CH3COOH \rightarrow H+ + CH3COO-
CH3COONa \rightarrow Na+ + CH3COO-


CH3COO- + H+ \rightarrow CH3COOH


The Attempt at a Solution


CH3COO- + H+ \rightarrow CH3COOH
I used the ICE table for this
and it turns out that the molarity of CH3COO- and H+ are both = 0 at equilibrium...
 
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Which suggests you have now solution of acetic acid and sodium nitrate... Take a look at stoichiometry of the mixture.

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