Chemicals that freeze at less than 60 Kelvin

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Discussion Overview

The discussion centers around identifying chemicals that freeze at temperatures below 60 Kelvin, with a specific interest in those that freeze below 50 Kelvin. Participants explore resources and references for finding this information, including organic molecules and elements.

Discussion Character

  • Exploratory
  • Technical explanation
  • Homework-related

Main Points Raised

  • One participant requests a reference list of chemicals that freeze below 50 K, noting that while many organic molecules do, they are unsure of specific examples.
  • Another participant suggests that Alfa Aesar has released a significant amount of chemical melting point data, which may be useful for finding relevant information.
  • This second participant also mentions that for temperatures around 100 K, silanes and certain conjugated organic chemicals might be more readily available, and recalls that methane freezes around 90 K.
  • A third participant recommends the CRC Handbook of Chemistry as a potential resource for this information.
  • Another participant provides a link to a melting point chart for elements but notes that it does not include deuterium, which freezes at about 19 K.

Areas of Agreement / Disagreement

Participants do not appear to reach a consensus on specific chemicals that freeze below 50 K, and multiple suggestions for resources and approaches are presented without definitive agreement on the best source.

Contextual Notes

Limitations include the potential difficulty in finding comprehensive lists of chemicals that freeze at such low temperatures and the reliance on specific databases or handbooks that may not cover all organic molecules.

Albertgauss
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Does anyone know of a reference to a list of all known chemicals that freeze at less than 50 K? I know lots of organic molecules do, but I don't know which ones. I also can find the freezing points of all the elements pretty easy, but chemicals are proving more elusive.
 
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Albertgauss said:
Does anyone know of a reference to a list of all known chemicals that freeze at less than 50 K? I know lots of organic molecules do, but I don't know which ones. I also can find the freezing points of all the elements pretty easy, but chemicals are proving more elusive.

Alfa Aesar just released a rather large amount of chemical melting point data the other year as part of an "open access" project. If you Google that, you should be able to find that information - as well as other related data sets that are part of this project.

My recollection is that you are probably best off not holding your breath. If you were looking for something around 100 K, you'd have better luck - silanes and certain conjugated organic chemicals can freeze around that point. Even methane freezes at around 90 K (as memory serves).

If you find anything interesting, though, please share! I'd sincerely love to see what you dig up.
 
CRC handbook of chemistry could be a good place to look
 

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