Chemistry - Equilibria questions involving ICE tables

Click For Summary
SUMMARY

The discussion focuses on the application of ICE tables in solving equilibria problems in chemistry, specifically regarding the simplification of the equilibrium constant expression (Ka). When Ka is significantly smaller than the initial concentration, it is valid to approximate x as negligible, allowing for simpler calculations. The 5% rule is introduced as a guideline, stating that x can be omitted if it is less than 5% of the initial concentration. This approximation is crucial for accurately determining the concentration of species at equilibrium without complicating the calculations.

PREREQUISITES
  • Understanding of equilibrium constants (Ka) in chemical reactions
  • Familiarity with ICE tables for calculating concentrations
  • Basic knowledge of weak acids and bases
  • Concept of percentage approximations in mathematical calculations
NEXT STEPS
  • Study the derivation and application of the 5% rule in chemical equilibria
  • Explore advanced examples of ICE tables with varying concentrations
  • Learn about the impact of temperature on equilibrium constants
  • Investigate the differences between strong and weak acids in equilibrium calculations
USEFUL FOR

Chemistry students, educators, and professionals involved in chemical equilibrium analysis, particularly those working with weak acids and bases.

EdTheHead
Messages
24
Reaction score
0
In my book for all these equilibria questions involving ice tables when I end up with Ka = \frac{(x)(x)}{initial amount - x} they always say that if the Ka is tiny compared to the initial amounts then we can assume x will be too and we can omit as many x's as we like from this equation. This obviously makes solving for x a whole lot easier but I don't get how this works.

First off a weak acid/base example
Ka = \frac{(x)(x)}{initial\ amount - x}
if I omit 1 x I get x = \sqrt{Ka(initial\ amount)}
if I omitted 2 x's I'd get x = Ka(initial\ amount) a completely different answer. Does this only apply if I have a (constant \pm x) then I just omit the plus/minus x?
 
Chemistry news on Phys.org
x can be omitted only in sums.

There is a rule of thumb (so called 5% rule) which says that a+x can be approximated by a if x is less than 5% of a. See here.

--
methods
 

Similar threads

  • · Replies 4 ·
Replies
4
Views
3K
  • · Replies 6 ·
Replies
6
Views
709
  • · Replies 8 ·
Replies
8
Views
2K
  • · Replies 2 ·
Replies
2
Views
2K
  • · Replies 2 ·
Replies
2
Views
16K
  • · Replies 7 ·
Replies
7
Views
2K
  • · Replies 2 ·
Replies
2
Views
7K
Replies
3
Views
2K
  • · Replies 2 ·
Replies
2
Views
2K
  • · Replies 7 ·
Replies
7
Views
4K