Chiral symmetries in E[SUP]^n[/SUP]

Click For Summary
SUMMARY

The discussion centers on chiral symmetries in Euclidean spaces, particularly focusing on tetrahedral molecules and their mirror-symmetric counterparts. It highlights that 2D geometries, such as triangles with unequal sides, can exhibit mirror-asymmetry when confined to their plane, demonstrating a parallel to 3D chiral figures. The conversation also explores the implications of reflections in higher dimensions, specifically through mappings in n-D Euclidean spaces, where transformations preserving the inner product are defined by x → Ax + b, with A being an orthogonal matrix. The significance of determinants in these transformations is emphasized, particularly the distinction between orientation-preserving and orientation-reversing mappings.

PREREQUISITES
  • Understanding of chirality in molecular structures
  • Familiarity with Euclidean geometry and congruency
  • Knowledge of linear algebra, specifically matrix transformations
  • Basic concepts of higher-dimensional spaces and mappings
NEXT STEPS
  • Research "Chirality in organic chemistry" to understand molecular implications
  • Study "Euclidean geometry and its properties" for foundational knowledge
  • Explore "Linear transformations and orthogonal matrices" in linear algebra
  • Investigate "Higher-dimensional geometry" and its applications
USEFUL FOR

Biochemists, mathematicians, and physicists interested in the implications of chirality and symmetry in molecular structures and higher-dimensional geometries.

Mark Harder
Messages
246
Reaction score
60
As a biochemist, I deal with chirality of molecules all the time. If you have a tetrahedral molecule, for example a carbon atom, and all 4 vertices are labeled differently, as in different atoms on each one, then that molecule has a mirror-symmetric one that cannot be superimposed on the original. This makes a big difference when it comes to binding of small chiral molecules to big ones, esp. enzymes. What about 2-D geometry? Are there figures, triangles for example, that are mirror-asymetric? The answer is yes, provided they are confined to the plane they are in. Flipping over is not an allowed move, since the triangles are confined to E^2.
Try it. Draw a triangle with each side of a different length. Draw a straight line parallel to one of the edges (not necessary, but it makes visualizing easier) and outside the triangle. Now 'reflect' the triangle about this 1-D 'mirror', i.e. draw a triangle with vertices at the same distances from the mirror as the original. Now try to mentally rigidly rotate and translate the triangles so that they superimpose. You can't do it (without breaking the law and rotating in the 3rd dimension.) This is a 2D analog of 3D chiral figures and 2D mirrors. Not that the angles (disregarding their directions) and included sides are the same, satisfying Euclid's definition of congruency.
Now try the 1D case. Draw a directed line segment on the number line. Locate a point (a 0-D figure) on the line outside the directed segment and 'reflect' the directed segment about the point. The result will be a directed line segment pointed in the opposite direction from the original - a 1-D, 0-D analog of higher dimensions. Obviously, there is no example for 0-D figures.
So, my question is, can these examples be extended to higher dimensions? To n-D Euclidean spaces in general? What about other geometries?
 
Physics news on Phys.org
The mappings from \mathbb{R}^n to itself which preserve the euclidean inner product are x \mapsto Ax + b where A^{-1} = A^T, so |\det A| = \pm 1. Those with \det A = -1 are reflections, which require "flipping" in an additional dimension.

In more general geometries, you can have distance- and angle-preserving mappings, which will either preserve orientation or reverse it.
 

Similar threads

  • · Replies 12 ·
Replies
12
Views
2K
  • · Replies 15 ·
Replies
15
Views
2K
  • · Replies 4 ·
Replies
4
Views
4K
  • · Replies 40 ·
2
Replies
40
Views
5K
  • · Replies 5 ·
Replies
5
Views
2K
  • · Replies 7 ·
Replies
7
Views
3K
  • · Replies 21 ·
Replies
21
Views
6K
  • · Replies 12 ·
Replies
12
Views
3K
  • · Replies 7 ·
Replies
7
Views
3K
  • · Replies 29 ·
Replies
29
Views
7K