Cold vs hot on the atomic scale

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Discussion Overview

The discussion revolves around the concepts of temperature at the atomic scale, particularly in relation to 0 Kelvin, the behavior of photons, and the processes involved in laser cooling of atoms. Participants explore the implications of temperature as a collective phenomenon and the nuances of cooling mechanisms.

Discussion Character

  • Exploratory
  • Technical explanation
  • Conceptual clarification
  • Debate/contested

Main Points Raised

  • One participant questions whether a photon in a vacuum can be considered the "hottest" particle due to its constant speed, suggesting that temperature is a collective phenomenon and cannot be assigned to individual particles.
  • Another participant clarifies that for a gas of photons, temperature relates to the distribution of their energy rather than their speed, as photons always travel at the speed of light.
  • Discussion on laser cooling indicates that while atoms are slowed down, this process is a form of cooling, but it is not solely about removing hotter atoms; there are limits to how low temperatures can be achieved through this method.
  • One participant introduces the idea that it may be meaningful to consider the temperature of a single atom when it is part of a heat bath, suggesting a Maxwell-Boltzmann distribution of states.
  • Another participant agrees with the previous point but emphasizes that an atom ceasing to move does not equate to it being at zero temperature.

Areas of Agreement / Disagreement

Participants generally agree on the collective nature of temperature and the mechanics of laser cooling, but there are nuances regarding the interpretation of temperature at the atomic level and the implications of an atom's motion.

Contextual Notes

There are unresolved aspects regarding the definitions of temperature in relation to individual particles and the implications of cooling processes, as well as the limitations of laser cooling techniques.

Fishpig
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TL;DR
slowest speed vs the fastest speed and temperature
So I've been hunting google for an answer but i cannot find a definitive one.

If 0 Kelvin is the coldest temperature and it is where atoms cease to move does this mean that a photon in a vacuum is the hottest particle because it is in turn moving at the fastest speed possible?

Second question is with cooling down the atoms they use a laser to push away the warmer particles until it's just the cold ones, so is it really "cooling" or are they just slowing them down? yes i do realize that it's both but it should be one or the other.

Thanks smart people.
 
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Fishpig said:
If 0 Kelvin is the coldest temperature and it is where atoms cease to move does this mean that a photon in a vacuum is the hottest particle because it is in turn moving at the fastest speed possible?
Temperature is a collective phenomenon. We cannot talk the temperature of one atom or one photon.

For a gas of photons, it is not their speed that is related to temperature, since they always move at ##c##. What we have is a distribution of the photons' energy (or frequency, or wavelength) that depends on temperature.

Fishpig said:
Second question is with cooling down the atoms they use a laser to push away the warmer particles until it's just the cold ones, so is it really "cooling" or are they just slowing them down? yes i do realize that it's both but it should be one or the other.
In laser cooling the atoms are slowed down. No experiment is perfect, but the cooling results from the slowing down, not from the loss of hot atoms.

However, there is a limit to the temperature that can be achieved by laser cooling (of the order of 1-10 μK), such that in experiments where lower temperatures are needed, for instance to achieve Bose-Einstein condensation, after the laser cooling phase there is an evaporative cooling phase, where cooling is obtained by letting the hottest atoms escape.
 
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That makes sense thank you, the laser is really just 1 part which i did know i just didn't know the order.
This site is brilliant because i have so many questions that i never knew who to ask.
 
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DrClaude said:
Temperature is a collective phenomenon. We cannot talk the temperature of one atom or one photon.
In principle that's right, but it can make well sense to consider the temperature of a single atom when it is coupled to some "heat bath", i.e., as an open quantum system. Then you expect the atomic states being Maxwell-Boltzmann distributed with the temperature given by the temperature of the heat bath.
 
vanhees71 said:
In principle that's right, but it can make well sense to consider the temperature of a single atom when it is coupled to some "heat bath", i.e., as an open quantum system. Then you expect the atomic states being Maxwell-Boltzmann distributed with the temperature given by the temperature of the heat bath.
I agree. I should have said that "We cannot talk the temperature of one atom or one photon in isolation."

I think however that it is important in the context of the OP to say that when an atom ceases to move, it does not mean that it is a zero temperature.
 
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