@Infrared Good observation! I see that I meant something different by 'coordinate function' from what you, quite reasonably, are taking it to mean. Further I suspect yours is the usual meaning. Let me try to explain what I meant by coordinate function.
What I had in mind for the ##j##th coordinate function was a function that mapped the ##j##th coordinate of a point ##\vec x\in \mathbb R^n## to the ##j##th coordinate of ##f(\vec x)##, where the coordinates are in a chosen coordinate system. That function would be a map from a subset of ##\mathbb R## to itself and so is not barred from being injective.
I'll try to formalise that as follows:
Let C be a coordinate system for ##\mathbb R^n##. That means there are subsets ##A_1,...,A_n## of ##\mathbb R##, projection functions ##p^C_j:\mathbb R_n\to A_j## for ##j=1,...,n## and a bijective coordinate map ##p^C:\mathbb R^n\to A_1\times...\times A_n## such that ##p^C(\vec x)=(p_1^C(\vec x), ...,p_n^C(\vec x))##.
Let ##S_j^C## be the Cartesian product of the ##A_1,...,A_n##, excluding ##A_j##, so it's a subset of ##\mathbb R^{n-1}##.
Then for ##\vec u\in S_j^C## define the function ##f^{C,j}_{\vec u}:A_j\to A_j## such that, for ##r\in A_j## we have ##f^{C,j}_{\vec u} (r)= p^C_j\circ f\circ \left(p^C\right)^{-1}\left((u_1,u_2,...,u_{j-1},r,u_j,...u_{n-1})\right)##.
With that background, what I meant by saying the ##j##th coordinate function of ##f## in coordinate system C is one-to-one is that ##f^{C,j}_{\vec u}## is one-to-one for all ##\vec u\in S_j##. To avoid confusion with the usual meaning, let's say that the '##f##-rank' of a coordinate system C is the number of dimensions ##j## such that ##f^{C,j}_\vec u## is injective for all ##\vec u\in S^C_j##
The question is then, for a given ##f##, what is the maximum ##f##-rank of any coordinate system for ##\mathbb R^n##, and which coordinate systems have that ##f##-rank?
We could then define the 'coordinate rank' of any function ##f:\mathbb R^n\to\mathbb R^n## as the maximum ##f##-rank of any coordinate system.
If ##f## is linear of rank ##n## and injective, I think any Cartesian coordinate system will have ##f##-rank equal ##n##, so the coordinate rank of ##f## is ##n##. I suspect that for injective, nonlinear functions, some coordinate systems may have ##f##-rank less than ##n## but there will be at least one whose ##f##-rank is ##n## so that the coordinate rank of ##f## is ##n##. But That's just a hunch. It may be that if we require continuity, for all injective ##f## all coordinate systems will have ##f##-rank ##n##.
Consider the function that maps every point P in ##\mathbb R^n## to the point where the ray OP (O is the origin) intersects an oblate spheroid surrounding the origin. In a Cartesian coordinate system C every ##f^{C,j}_\vec u## will be non-injective. But if C is a hyper-polar coordinate system, ##f^{C,j}_\vec u## will be injective for every ##j## other than 1, where we take dimension 1 to be the radial coordinate. So C will have ##f##-rank ##n-1## and ##f## will have coordinate rank ##n-1##.
Another one to consider is where ##f## is the projection function onto a ##(n-1)##-dimensional hyperplane through the origin. Most Cartesian coordinate systems will have ##f##-rank zero. But the coordinate system whose basis vectors are an orthogonal basis for the hyperplane together with a vector normal to it, will have ##f##-rank ##n-1##, as the functions ##f_\vec u^{C,j}## are all the identity function on ##\mathbb R##, where ##j## is the dimension of one of the basis vectors of the hyperplane.
The coordinate rank of a function would be a measure of how much it reduces the dimensionality of its domain. For nonlinear functions, the reduction in dimensionality may vary between different parts of the domain.