Debye-Hückel Rule: Relaxation Effects in Electric Fields

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Discussion Overview

The discussion revolves around the Debye-Hückel Rule and its implications regarding relaxation effects in electrolytes when subjected to an electric field. Participants seek to clarify the nature of these effects and the role of electric fields in this context.

Discussion Character

  • Exploratory, Technical explanation, Debate/contested

Main Points Raised

  • Faisal questions how relaxation effects occur under the influence of an electric field, suggesting a logical inconsistency.
  • Another participant requests clarification on what specific aspect of relaxation is being referred to.
  • Faisal later specifies that he is interested in the relaxation of molecules in the electrolyte when an electric field is applied.
  • One participant proposes that the relaxation involves the reshaping of the ionic cloud following the movement of a central ion.
  • This participant also argues that while the electric field can shift the equilibrium positions of ions, it should not halt the relaxation process.

Areas of Agreement / Disagreement

Participants express differing views on the impact of the electric field on relaxation effects, with no consensus reached on the fundamental question posed by Faisal.

Contextual Notes

There are unresolved assumptions regarding the definitions of relaxation and the specific mechanisms at play in the presence of an electric field.

Deadevil
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Dear Fellows,
In Debye Huckle Rule, how does Relaxation effect occurs in the presence of electric field.Logically it is not possible in the presence of electric field.Please help me out.

Thanks
Faisal
 
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Plz Plz Plz Reply this question i m an urgent need for this explanation.PLZZZ help out..
 
I fear I don't quite understand your question. Relaxation of what?
Maybe you can extend the description of what exactly you are interested in?

Btw, the second guy is called "Hückel", not Huckle.
 
Sorry for Huckel:-) relaxation effect of the molecules in the electrolyte when the electric field is applied..??
 
OK, you mean reshaping of the ionic cloud after the "central" ion moved.

Why would the electric field stop the process? It can shift the equilibrium positions of ions, but it won't stop the relaxation.
 

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