Degenerate Perturbation Theory Wavefunction Correction

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SUMMARY

This discussion centers on the application of degenerate perturbation theory in quantum mechanics, specifically addressing the wavefunction correction for non-degenerate and degenerate states. The formula for the first-order wavefunction correction is presented as |\psi_{n}^{(1)}> = \sum \frac{<\psi_{m}^{(0)}|V|\psi_{n}^{(0)}>}{E_n^{(0)} - E_m^{(0)}}\psi_m^{(0)}, with the distinction that for degenerate states, the summation excludes states within the degenerate subspace. The participant questions the consistency of having identical wavefunction corrections across different "good" states while their energy corrections differ, ultimately realizing that the matrix elements indeed vary for different states.

PREREQUISITES
  • Understanding of quantum mechanics, specifically Hamiltonians and perturbation theory.
  • Familiarity with the concepts of wavefunctions and eigenstates.
  • Knowledge of matrix elements in quantum mechanics.
  • Basic grasp of degenerate versus non-degenerate states in quantum systems.
NEXT STEPS
  • Study Griffiths' "Introduction to Quantum Mechanics" for detailed insights on degenerate perturbation theory.
  • Learn about the mathematical derivation of matrix elements in quantum mechanics.
  • Explore advanced topics in perturbation theory, including higher-order corrections.
  • Investigate applications of perturbation theory in various quantum systems, such as atoms and molecules.
USEFUL FOR

This discussion is beneficial for quantum mechanics students, physicists specializing in theoretical physics, and researchers working on perturbation theory applications in quantum systems.

McLaren Rulez
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Hi,

If we have a non degenerate solution to a Hamiltonian and we perturb it with a perturbation V, we get the new solution by

|\psi_{n}^{(1)}&gt; = \sum \frac{&lt;\psi_{m}^{(0)}|V|\psi_{n}^{(0)}&gt;}{E_n^{(0)} - E_m^{(0)}}\psi_m^{(0)}

where we sum over all m such that m\neq n.

When we do the same for a degenerate perturbation theory, we simply exclude all the \psi_m that belongs to the degenerate subspace. That is

|\psi_{n}^{(1)}&gt; = \sum \frac{&lt;\psi_{m}^{(0)}|V|\psi_{n}^{(0)}&gt;}{E_n^{(0)} - E_m^{(0)}}\psi_m^{(0)}

only this time the summation exculdes m if \psi_{m} is in the degenerate subspace. Am I right so far?

If so, my question is this. Assuming we are taking the "good" states that Griffiths mentions (those which are the eigenstates of V in the degenerate subspace), then each one has a different energy correction. But the wavefunction correction for all of them is exactly the same according to the expression given above. That seems a little fishy. The first order corrections to each of the "good" states is exactly the same but the first order energy correction is different?

Thank you for your help.
 
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The matrix elements \langle \psi_m^{(0)}|V|\psi_n^{0)}\rangle will be different for different "good states" n from the degenerate subspace, no?
 
Oh dear, I don't know what I was thinking! Sorry about that. It is obviously different for different n. Thank you DrDu.
 

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