Determining pH when given volume and concentration of a solution?

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To determine the pH of a 50 mL 0.1 M Tris solution in its acid form, the Henderson-Hasselbalch equation is applicable, but clarification on what "Tris solution (in acid form)" means is necessary. The discussion highlights confusion regarding whether this refers to Tris hydrochloride or another form of Tris. When 2 mL of 1 M NaOH is added to the solution, the pH will change, necessitating recalculation using the new concentrations. Understanding the specific form of Tris is crucial for accurate pH determination. The conversation emphasizes the importance of defining chemical terms for effective problem-solving.
Violagirl
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Homework Statement



I'm stuck on these two problems:

A) IF you make a 50 mL of a 0.1 M Tris solution (in acid form), what will be the pH?

B) If you add 2 mL of 1 M NaOH to the above solution, what will be the pH?

Homework Equations



pH = pka + log [A/HA] Hendersen-Hasselbalch

The Attempt at a Solution



I'm not sure if HH is the right equation to use or not for this one when given both volume and concentration or if you add the NaOH to it. Help is greatly appreciated.
 
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Violagirl said:

Homework Statement



I'm stuck on these two problems:

A) IF you make a 50 mL of a 0.1 M Tris solution (in acid form), what will be the pH?

B) If you add 2 mL of 1 M NaOH to the above solution, what will be the pH?

Homework Equations



pH = pka + log [A/HA] Hendersen-Hasselbalch

The Attempt at a Solution



I'm not sure if HH is the right equation to use or not for this one when given both volume and concentration or if you add the NaOH to it. Help is greatly appreciated.

It would help if you could define what "Tris solution (in acid form)" is.
 
I'm not sure, that is the exact way that the question was asked...Is it referring to a Tris buffer of a 100% solution?
 
I can only repeat after Pranav-Arora - what does it mean "Tris in acid form"? What other forms can Tris have?
 
This might help you...
160px-Tris.png

http://en.wikipedia.org/wiki/Tris
 
Last edited:
You can buy tris which they call tris base (HOCH2)3CNH2, and you can buy tris hydrochloride (crystalline) (HOCH2)3CNH3+Cl-, I think the latter is what they must mean.
 

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