Determining Solubility in Acidic Solutions / Pure Water

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SUMMARY

The discussion centers on the solubility of various compounds in acidic solutions compared to pure water. The compounds analyzed include FeS, CuCN, AlPO4, BaCO3, and AgCl. It is established that FeS, CuCN, AlPO4, and BaCO3 are more soluble in acid due to their conjugate bases being weak acids, while AgCl, with a conjugate base of a strong acid (HCl), is not more soluble. The final conclusion is that only AgCl does not increase in solubility in acidic conditions, leading to the answer of 1 compound that is less soluble in acid.

PREREQUISITES
  • Understanding of acid-base chemistry and solubility principles
  • Knowledge of weak and strong acids, specifically H2S, HCN, H3PO4, and HCl
  • Familiarity with the concept of conjugate bases
  • Basic chemical reaction equations involving solubility
NEXT STEPS
  • Research the solubility rules for ionic compounds in acidic solutions
  • Study the properties of weak acids and their conjugate bases
  • Explore the effects of pH on the solubility of various salts
  • Investigate the role of common ions in solubility equilibria
USEFUL FOR

Chemistry students, educators, and professionals involved in chemical analysis or environmental science, particularly those focusing on solubility and acid-base reactions.

JwdePhysics
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Homework Statement


How many of the following would you NOT expect to be more soluble in acid than in pure water?

FeS, CuCN, AlPO4, BaCO3, AgCl

Homework Equations


None necessary

The Attempt at a Solution


So we know that anything with OH- or anything that has the conjugate base of a weak acid will be more soluble in acidic solution than pure water. Since there is nothing with OH-, we don't have to worry about that. Now the strong acids are H2SO4, HNO3, HBR, HI, HCLO4, and HCL.

1. FeS has the conjugate base of a weak acid, H2S, therefore it is more soluble in acid than in pure water, therefore it doesn't contribute to the answer
2.CuCN has the conjugate base of a weak acid, HCN, therefore it is more soluble in acid than in pure water, therefore it doesn't contribute to the answer
3.AlPO4 has the conjugate base of a weak acid, H3PO4, therefore it is more soluble in acid than in pure water, therefore it doesn't contribute to the answer
4.BaCO3 has the conjugate base of a weak acid, HCO3, therefore it is more soluble in acid than in pure water, therefore it doesn't contribute to the answer
5. AgCl has the conjugate base of a strong acid, HCL, therefore it is NOT more soluble in acid than in pure water, therefore it contributes to the answer

Therefore the answer should be 1.

Is my logic right or wrong?
 
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Your logic looks OK, yet the final answer is blatantly wrong and it contradicts everything you wrote earlier. I suppose it is just kind of typo.
 
I think he means the number is 1 (answering the asked question "how many?"), rather than No.1 (answering the not-asked question "Which?")
 
Ah, could be. Thanks.
 

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