Determining Solubility in Acidic Solutions / Pure Water

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Discussion Overview

The discussion revolves around the solubility of various compounds in acidic solutions compared to pure water, specifically focusing on whether certain compounds would be more or less soluble in acid. The context is homework-related, involving reasoning about chemical principles and solubility rules.

Discussion Character

  • Homework-related, Conceptual clarification, Debate/contested

Main Points Raised

  • One participant asserts that compounds with the conjugate base of a weak acid will be more soluble in acidic solutions, providing examples such as FeS, CuCN, AlPO4, and BaCO3.
  • The same participant claims that AgCl, having the conjugate base of a strong acid, will not be more soluble in acid than in pure water.
  • Another participant points out a contradiction in the final answer given by the first participant, suggesting it may be a typo.
  • A third participant interprets the original question as asking for the number of compounds that would not be more soluble in acid, rather than identifying which specific compound that would be.

Areas of Agreement / Disagreement

There is disagreement regarding the final answer provided by the first participant, with some suggesting it may be incorrect or misinterpreted. The discussion does not reach a consensus on the correct answer.

Contextual Notes

Participants express uncertainty about the interpretation of the question and the implications of the solubility rules discussed. There is a lack of clarity on whether the final answer aligns with the reasoning presented.

Who May Find This Useful

Students studying solubility principles in chemistry, particularly in the context of acidic solutions and homework assignments related to chemical equilibria.

JwdePhysics
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Homework Statement


How many of the following would you NOT expect to be more soluble in acid than in pure water?

FeS, CuCN, AlPO4, BaCO3, AgCl

Homework Equations


None necessary

The Attempt at a Solution


So we know that anything with OH- or anything that has the conjugate base of a weak acid will be more soluble in acidic solution than pure water. Since there is nothing with OH-, we don't have to worry about that. Now the strong acids are H2SO4, HNO3, HBR, HI, HCLO4, and HCL.

1. FeS has the conjugate base of a weak acid, H2S, therefore it is more soluble in acid than in pure water, therefore it doesn't contribute to the answer
2.CuCN has the conjugate base of a weak acid, HCN, therefore it is more soluble in acid than in pure water, therefore it doesn't contribute to the answer
3.AlPO4 has the conjugate base of a weak acid, H3PO4, therefore it is more soluble in acid than in pure water, therefore it doesn't contribute to the answer
4.BaCO3 has the conjugate base of a weak acid, HCO3, therefore it is more soluble in acid than in pure water, therefore it doesn't contribute to the answer
5. AgCl has the conjugate base of a strong acid, HCL, therefore it is NOT more soluble in acid than in pure water, therefore it contributes to the answer

Therefore the answer should be 1.

Is my logic right or wrong?
 
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Your logic looks OK, yet the final answer is blatantly wrong and it contradicts everything you wrote earlier. I suppose it is just kind of typo.
 
I think he means the number is 1 (answering the asked question "how many?"), rather than No.1 (answering the not-asked question "Which?")
 
Ah, could be. Thanks.
 

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