Dimensionality of total angular momentum space

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SUMMARY

The dimensionality of total angular momentum space for two electrons, one with quantum numbers n=1, l=0 and the other with n=2, l=1, is determined by the combination of their spins and orbital angular momenta. The total spin can be either s=0 or s=1, leading to different total angular momentum states. For the combination of s=1 and l=1, the possible values of j are 1 and 2, resulting in a total of 9 states when considering all combinations of m_s and m_l. The correct dimensionality is confirmed to be 9 states, not 15 as initially calculated.

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  • Understanding of quantum mechanics, specifically angular momentum
  • Familiarity with quantum numbers (n, l, s, j)
  • Knowledge of the rules for addition of angular momenta
  • Ability to interpret state notation in quantum mechanics
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xago
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Homework Statement



There are 2 electrons, one with n=1, l=0 and the other with n=2, l=1. The question asks what is the dimensionality of total angular momentum space.

Homework Equations


(2j_{1}+1)(2j_{2}+1)

The Attempt at a Solution


I know for 2 electrons (spin 1/2 each) the possible values of total spin are s=0 or s=1.
the total angular momentum is l=0 + l=1 = 1 (right?)
So does this mean that j1 = 1+0 and j2 = 1+1
which gives a dimensionality of (2(1) +1)(2(2) +1) = 15??
The number seems a little off to me, perhaps the equation I have for dimensionality is incorrect?
 
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Take the s=0, l=1 combination. Your formula says there are (2s+1)(2l+1) = 3 total states. Those states are
\begin{align*}
&\vert s=0,\ m_s=0;\ l=1,\ m_l=1\rangle \\
&\vert s=0,\ m_s=0;\ l=1,\ m_l=0\rangle \\
&\vert s=0,\ m_s=0;\ l=1,\ m_l=-1\rangle.
\end{align*}The other way to look at it is to sum the angular momenta together, ##\vec{J} = \vec{S} + \vec{L}##. According to the rules of addition of angular momenta, there is only a single allowed value for j, namely j=1, so there are 2j+1 = 3 states, corresponding to mj = 1, 0, and -1. Either way you get three states.

Now you do the s=1, l=1 combination. What are the allowed values of j?
 
vela said:
Take the s=0, l=1 combination. Your formula says there are (2s+1)(2l+1) = 3 total states. Those states are
\begin{align*}
&\vert s=0,\ m_s=0;\ l=1,\ m_l=1\rangle \\
&\vert s=0,\ m_s=0;\ l=1,\ m_l=0\rangle \\
&\vert s=0,\ m_s=0;\ l=1,\ m_l=-1\rangle.
\end{align*}The other way to look at it is to sum the angular momenta together, ##\vec{J} = \vec{S} + \vec{L}##. According to the rules of addition of angular momenta, there is only a single allowed value for j, namely j=1, so there are 2j+1 = 3 states, corresponding to mj = 1, 0, and -1. Either way you get three states.

Now you do the s=1, l=1 combination. What are the allowed values of j?

So if I understand correctly, j= l+s = 2 for l=1, s=1 which means that the possible values of m_{j} are -2,-1,0,1,2 which gives the possible states of:
\begin{align*}
&\vert s=1,\ m_s=-1;\ l=1,\ m_l=1\rangle \\
&\vert s=1,\ m_s=-1;\ l=1,\ m_l=0\rangle \\
&\vert s=1,\ m_s=-1;\ l=1,\ m_l=-1\rangle \\
&\vert s=1,\ m_s=0;\ l=1,\ m_l=1\rangle \\
&\vert s=1,\ m_s=0;\ l=1,\ m_l=0\rangle \\
&\vert s=1,\ m_s=0;\ l=1,\ m_l=-1\rangle \\
&\vert s=1,\ m_s=1;\ l=1,\ m_l=1\rangle \\
&\vert s=1,\ m_s=1;\ l=1,\ m_l=0\rangle \\
&\vert s=1,\ m_s=1;\ l=1,\ m_l=-1\rangle.
\end{align*}

which gives 9 states total... (including the 3 states in the middle there which are the same as the ones given by s=0)
 
Last edited:
No, that's not correct. I think you need to go back and study the addition of angular momenta as you seem to have some basic misunderstandings about angular momentum in quantum mechanics.
 
I just re-edited my 2nd post there, i confused m_{j} with m_{s}, but I know that for s=1 m_{s} is -1,0,1 which combined with m_{l} =-1,0,1 gives 9 states in total including the 3 given by s=0 right?
 
Yes, there are nine states. (You meant ms and ml, not mj.)

But think about this. If j=2, then mj can be -2, -1, 0, 1, 2. That's five states. What are the other four in the |j mj> basis?
 
Would those be the case where only one spin is taken into account aka s=1/2, -1/2
which gives m_{j}= -3/2, -1/2, 1/2, 3/2

also, just to clarify, the only possible values for j are 1 and 2 right?
 
Last edited:
xago said:
Would those be the case where only one spin is taken into account aka s=1/2, -1/2
which gives m_{j}= -3/2, -1/2, 1/2, 3/2
No.

also, just to clarify, the only possible values for j are 1 and 2 right?
No.
 

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