Do we need salt bridges in Electrolytic cells?

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SUMMARY

Salt bridges are essential in electrolytic cells to neutralize charge imbalances and maintain a consistent current flow. Without a salt bridge, the potential difference across the electrolytic cell increases, potentially exceeding the generator's capacity to supply current. While didactic materials often illustrate salt bridges in galvanic cells, their necessity in electrolytic cells is equally critical for circuit closure and operational efficiency.

PREREQUISITES
  • Understanding of electrolytic cell operation
  • Knowledge of charge neutrality in electrochemical systems
  • Familiarity with circuit closure principles
  • Basic concepts of galvanic versus electrolytic cells
NEXT STEPS
  • Research the role of salt bridges in electrochemical cells
  • Explore the differences between galvanic and electrolytic cells
  • Learn about the components of an electrolytic cell circuit
  • Study the effects of charge imbalance on electrochemical reactions
USEFUL FOR

Chemistry students, electrochemists, and anyone involved in designing or studying electrochemical cells will benefit from this discussion.

jaumzaum
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I was wondering if we really need salt bridges when doing Electrolysis. I would answer yes, because we need to neutralize the charges in both sides, or the potential difference of the Electrolytic cell will keep increasing until the generator that is connected to it is not able to supply any current. But why all the pictures in the didactic chemistry books I read make sure they put a salt bridge or a membrane in a Galvanic Cell, but they never put it in a Electrolytic cell? Is it not necessary? If so, why?
 
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Think in terms of closing the circuit.
 
Borek said:
Think in terms of closing the circuit.
Sorry, I didn't get what you mean. The salt bridge would actually help to "close" the circuit, wouldn't it?
 
Yes.

Draw a full circuit (cell and all surrounding elements) containing an electrolytic cell and a a full circuit with a galvanic cell. Try to mark a closed current path for each circuit.
 

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