EM Theory: Refractive index of water

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SUMMARY

The refractive index of sea water is approximately 1.34, despite a low-frequency dielectric constant (k) of 80. This discrepancy arises because the refractive index is frequency-dependent, a phenomenon known as dispersion. The relationship n = √k, derived from Maxwell's equations, is only applicable to simple gases and does not hold for water. The dispersion equation n²(ω) = 1 + A (1/(ω₀² - ω²)) illustrates that at low frequencies, the refractive index exceeds 1 due to resonance effects.

PREREQUISITES
  • Understanding of dielectric constants and their significance in optics
  • Familiarity with Maxwell's equations and their application to refractive index calculations
  • Knowledge of dispersion and its impact on the refractive index
  • Basic concepts of frequency dependence in optical materials
NEXT STEPS
  • Study the principles of dielectric materials and their optical properties
  • Learn about the dispersion relation in optics and its mathematical formulation
  • Explore the frequency-dependent behavior of various materials, particularly water
  • Review Maxwell's equations in the context of electromagnetic wave propagation
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Students and professionals in physics, optical engineering, and materials science who are interested in understanding the optical properties of water and other dielectric materials.

samreen
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Homework Statement




Problem: Sea water has k = 80 in the low frequency limit. Yet its refractive index is around 1.34. Explain the discrepancy



Homework Equations



For a non magnetic dielectric medium, the absolute refractive index in the low frequency range, is given by : n = √k where k = Є/ Єo is the dielectric constant of the medium. Є and Єo are the permittivities of the medium and free space, respectively.




The Attempt at a Solution



No idea. Does it have anything to do with the fact that water shows a wide variety of behaviour in various frequency ranges?
 
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Note: this relation n \simeq \sqrt{K_{\epsilon}} (Maxwell Relation) only holds for simple gases (air, Helium, Hydrogen).

For water, this relation doesn't work well because K_{\epsilon} and then n are actually frequency-dependent, known as 'dispersion'.
You can consult to your Optics book for the dispersion eqn. I only summarize dispersion eqn, as:

n^2(\omega) = 1 + A (\frac{1}{\omega^2_0 - \omega^2}), A is constant value.


you see, if the frequency (\omega)is low (as your question) than resonance \omega_0, the refractive index will be greater than 1. so in case for sea water, n is about 1.34
 

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