Ethanol Dissolving: Molecules Stay Intact?

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SUMMARY

Ethanol remains intact as individual molecules when dissolved in water, contrasting with substances like sodium chloride that dissociate into ions. The interaction between ethanol and water is characterized by dynamic intermolecular interactions, primarily hydrogen bonding, which are transient in nature. Ethanol's significant pKa indicates that while hydrogen ions are transferred among water molecules, the ethanol molecules themselves do not ionize in solution. This understanding is particularly relevant for biochemists, although it holds less importance in undergraduate chemistry contexts.

PREREQUISITES
  • Understanding of intermolecular forces, particularly hydrogen bonding
  • Familiarity with the concept of pKa in chemistry
  • Basic knowledge of solubility and dissolution processes
  • Awareness of the differences between ionic and molecular compounds in solution
NEXT STEPS
  • Research the role of hydrogen bonding in solvent interactions
  • Explore the significance of pKa in biochemical reactions
  • Investigate the differences between strong and weak acids in solution
  • Learn about the dynamics of molecular interactions in aqueous solutions
USEFUL FOR

Chemistry students, biochemists, and anyone interested in the molecular behavior of solvents and solutes, particularly in the context of ethanol and water interactions.

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When ethanol dissolves, the individual molecules stay intact right? It doesn't dissolve like a hydrohalic acid in which the polar bond actually breaks?
 
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Right, ethanol does not break into ions in solution as say...Sodium Chloride would.
When ethanol is put into solution, the molecule stays together.

Ethanol (l) --H2O--> Ethanol (aq)
 
Actually its more of a dynamic interaction between water and ethanol, same with water-water interactions. That is the intermolecular interactions are transient, the hydrogens are transferred throughout the solution; also note that ethanol has a significant pKa.
 
GCT said:
the hydrogens are transferred throughout the solution; also note that ethanol has a significant pKa.
Really? Obviously there would be some significant Hydrogen bonding going on, but it actually gets ionized?
 
Yeah, even with water, the hydrogen bonds are transient, however the lifetimes of these bonds relative to other weaker intermolecular bonds e.g. small van der wall interactions, are somewhat greater. The hydrogen ions are passed between the water molecules, even at a pH of 7. Biochemists take this perspective more seriously, although it is somewhat less important for undergraduate chemistry.
 

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