Exothermic reaction of zeolite and water

Click For Summary
SUMMARY

The discussion focuses on the exothermic reaction between zeolites and water, highlighting their applications in the heating industry, particularly as solar thermal collectors and in adsorption refrigeration. The reaction's heat release depends on the standard reaction enthalpy and the heat capacity of the mixture. The temperature rise from mixing 100 grams of dry zeolites with 100ml of water at room temperature is influenced by the specific type of zeolite used, with estimates suggesting a heat capacity significantly lower than that of water.

PREREQUISITES
  • Understanding of exothermic reactions and thermodynamics
  • Familiarity with zeolite properties and applications
  • Knowledge of heat capacity and reaction enthalpy concepts
  • Basic principles of thermal insulation techniques
NEXT STEPS
  • Research specific types of zeolites and their thermal properties
  • Explore the calculation of reaction enthalpy for zeolite-water interactions
  • Investigate thermal insulation methods to maintain temperature in exothermic reactions
  • Learn about the applications of zeolites in solar thermal energy systems
USEFUL FOR

Researchers in materials science, engineers in the heating industry, and professionals involved in thermal energy management will benefit from this discussion.

ErikL
Messages
8
Reaction score
0
So, I was reading about zeolites:
https://en.wikipedia.org/wiki/Zeolite

One of the things it is used for, is in the heating industry, namely:
"Zeolites can be used as solar thermal collectors and for adsorption refrigeration. In these applications, their high heat of adsorptionand ability to hydrate and dehydrate while maintaining structural stability is exploited. This hygroscopic property coupled with an inherent exothermic (energy releasing) reaction when transitioning from a dehydrated to a hydrated form make natural zeolites useful in harvesting waste heat and solar heat energy. Zeolites are also used as a molecular sieve in cryosorption style vacuum pumps.[13]"

The question is, how hot does the exothermic reaction get? how long the zeolites stay warm in room temperature?
 
Chemistry news on Phys.org
ErikL said:
The question is, how hot does the exothermic reaction get?

This isn't the right question. Reaction doesn't "get hot". Reaction mixture or reactants get hot. How hot can it get? Depends on the standard reaction enthalpy and the heat capacity of the mixture.

how long the zeolites stay warm in room temperature?

Depends on the insulation and external temperature. With some tricks you can keep them at constant temperature (despite reaction being exothermic) or hot for months (after reaction ended).
 
Ok let me pin point my question - what is the temperature rise I can expect to get out of 100 grams of dry zeolites and 100ml of water at room temperature, mixed together?
 
A lot depends on the particular zeolite, but to get some rough numbers: quick googling shows this table. Heat capacity of the mixture will be well below that of water - say half of 4.2 J/gK.
 

Similar threads

Replies
8
Views
8K
  • · Replies 1 ·
Replies
1
Views
2K
  • · Replies 8 ·
Replies
8
Views
3K
Replies
7
Views
3K
  • · Replies 23 ·
Replies
23
Views
6K
  • · Replies 3 ·
Replies
3
Views
5K
  • · Replies 6 ·
Replies
6
Views
2K
  • · Replies 3 ·
Replies
3
Views
4K
  • · Replies 20 ·
Replies
20
Views
9K
  • · Replies 46 ·
2
Replies
46
Views
15K