Exothermic reaction of zeolite and water

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Discussion Overview

The discussion revolves around the exothermic reaction of zeolites when mixed with water, focusing on the temperature rise expected from this reaction and the duration for which the zeolites remain warm at room temperature. The scope includes theoretical aspects of thermodynamics and practical implications in heating applications.

Discussion Character

  • Exploratory
  • Technical explanation
  • Debate/contested

Main Points Raised

  • Some participants note that zeolites are used in heating applications due to their exothermic reaction when transitioning from a dehydrated to a hydrated state.
  • One participant emphasizes that the temperature increase depends on the standard reaction enthalpy and the heat capacity of the mixture, rather than the reaction itself getting hot.
  • Another participant seeks to clarify the expected temperature rise from mixing 100 grams of dry zeolites with 100 ml of water at room temperature.
  • A later reply suggests that the heat capacity of the zeolite-water mixture will be significantly lower than that of water, proposing a rough estimate based on quick research.

Areas of Agreement / Disagreement

Participants express differing views on how to frame the question regarding temperature changes and the factors influencing the heat generated by the reaction. The discussion remains unresolved regarding the specific temperature rise and the conditions affecting the duration of warmth.

Contextual Notes

Limitations include the dependence on the specific type of zeolite used, the assumptions about heat capacity, and the lack of detailed calculations or empirical data to support claims made in the discussion.

ErikL
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So, I was reading about zeolites:
https://en.wikipedia.org/wiki/Zeolite

One of the things it is used for, is in the heating industry, namely:
"Zeolites can be used as solar thermal collectors and for adsorption refrigeration. In these applications, their high heat of adsorptionand ability to hydrate and dehydrate while maintaining structural stability is exploited. This hygroscopic property coupled with an inherent exothermic (energy releasing) reaction when transitioning from a dehydrated to a hydrated form make natural zeolites useful in harvesting waste heat and solar heat energy. Zeolites are also used as a molecular sieve in cryosorption style vacuum pumps.[13]"

The question is, how hot does the exothermic reaction get? how long the zeolites stay warm in room temperature?
 
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ErikL said:
The question is, how hot does the exothermic reaction get?

This isn't the right question. Reaction doesn't "get hot". Reaction mixture or reactants get hot. How hot can it get? Depends on the standard reaction enthalpy and the heat capacity of the mixture.

how long the zeolites stay warm in room temperature?

Depends on the insulation and external temperature. With some tricks you can keep them at constant temperature (despite reaction being exothermic) or hot for months (after reaction ended).
 
Ok let me pin point my question - what is the temperature rise I can expect to get out of 100 grams of dry zeolites and 100ml of water at room temperature, mixed together?
 
A lot depends on the particular zeolite, but to get some rough numbers: quick googling shows this table. Heat capacity of the mixture will be well below that of water - say half of 4.2 J/gK.
 

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