Exothermic reaction of zeolite and water

In summary: Heat of reaction is 70-200 kJ/mol.In summary, Zeolites are a type of mineral that can be used in various applications, including solar thermal collectors and adsorption refrigeration. They have a high heat of adsorption and can hydrate and dehydrate while maintaining structural stability. This allows them to be used in harvesting waste heat and solar heat energy. Zeolites are also used as a molecular sieve and can stay warm for months after the reaction has ended. The temperature rise that can be expected from a mixture of 100 grams of dry zeolites and 100ml of water at room temperature will depend on the specific type of zeolite, but it can be estimated to be around 35-100 degrees
  • #1
ErikL
8
0
So, I was reading about zeolites:
https://en.wikipedia.org/wiki/Zeolite

One of the things it is used for, is in the heating industry, namely:
"Zeolites can be used as solar thermal collectors and for adsorption refrigeration. In these applications, their high heat of adsorptionand ability to hydrate and dehydrate while maintaining structural stability is exploited. This hygroscopic property coupled with an inherent exothermic (energy releasing) reaction when transitioning from a dehydrated to a hydrated form make natural zeolites useful in harvesting waste heat and solar heat energy. Zeolites are also used as a molecular sieve in cryosorption style vacuum pumps.[13]"

The question is, how hot does the exothermic reaction get? how long the zeolites stay warm in room temperature?
 
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  • #2
ErikL said:
The question is, how hot does the exothermic reaction get?

This isn't the right question. Reaction doesn't "get hot". Reaction mixture or reactants get hot. How hot can it get? Depends on the standard reaction enthalpy and the heat capacity of the mixture.

how long the zeolites stay warm in room temperature?

Depends on the insulation and external temperature. With some tricks you can keep them at constant temperature (despite reaction being exothermic) or hot for months (after reaction ended).
 
  • #3
Ok let me pin point my question - what is the temperature rise I can expect to get out of 100 grams of dry zeolites and 100ml of water at room temperature, mixed together?
 
  • #4
A lot depends on the particular zeolite, but to get some rough numbers: quick googling shows this table. Heat capacity of the mixture will be well below that of water - say half of 4.2 J/gK.
 

1. What is an exothermic reaction?

An exothermic reaction is a chemical reaction in which energy is released in the form of heat. This means that the products of the reaction have less energy than the reactants, and the excess energy is given off as heat.

2. What is zeolite?

Zeolite is a naturally occurring mineral made up of hydrated aluminosilicates. It has a unique porous structure that allows it to trap and release molecules, making it useful in various industrial and scientific applications.

3. How does the exothermic reaction of zeolite and water work?

When zeolite is exposed to water, the water molecules are able to enter the pores of the zeolite and interact with the positively charged ions within its structure. This interaction causes a rearrangement of the ions, releasing energy in the form of heat.

4. What are some common uses of the exothermic reaction of zeolite and water?

One common use of this reaction is in self-heating food and beverage packaging, where zeolite is mixed with water and placed in a separate chamber within the packaging. When the two substances come into contact, the reaction produces heat, warming up the food or beverage without the need for external heat sources. Zeolite-water reactions are also used in some hand warmers and heating pads.

5. Are there any safety concerns associated with this reaction?

While the exothermic reaction of zeolite and water is generally safe, it is important to handle zeolite with care as it can cause irritation if it comes into contact with skin or eyes. In addition, care must be taken to avoid inhaling any dust particles from the zeolite, as they can irritate the respiratory system. As with any chemical reaction, it is important to follow proper safety protocols and handle the substances responsibly.

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