Explaining the Anomaly in Atomic Radii of Transition Metals

Click For Summary
SUMMARY

The discussion focuses on the anomaly in atomic radii among transition metals, specifically highlighting that while atomic radii generally decrease across a period, transition metals exhibit a unique trend. For instance, scandium (Sc) has an atomic radius of 162 pm, decreasing to nickel (Ni) at 124 pm, but then increases for copper (Cu) and zinc (Zn). This anomaly is attributed to electron-electron repulsion within the electron shells, which contributes to an increase in atomic radius despite the increasing nuclear charge.

PREREQUISITES
  • Understanding of atomic structure and electron configuration
  • Familiarity with periodic trends in atomic radii
  • Knowledge of transition metals and their properties
  • Basic principles of electron-electron repulsion
NEXT STEPS
  • Research the electron configurations of transition metals
  • Study periodic trends in atomic and ionic radii
  • Explore the concept of electron shielding and its effects
  • Investigate the role of d-orbitals in transition metal chemistry
USEFUL FOR

Chemistry students, educators, and researchers interested in the properties of transition metals and atomic structure anomalies.

sciencenerd
Messages
3
Reaction score
0
Could anybody help me with this?

The atomic radii of the transition metals show some anomaly in their atomic radii as
compared to those elements in Group 1A-7A, which generally shows a decrease as one
goes from left to right in a period. The atomic radii of the transition metals decrease as
do those in Groups 1A-7A, but then they increase. For example, Sc has an atomic radius
of 162 pm and the atomic radii decrease until Ni to 124 pm, but Cu an Zn have larger
atomic radii than Ni and Zn is even larger than Cu. How do you explain this?
 
Physics news on Phys.org
Sciencenerd,
It is due to the repulsion between the electrons of the shells which increases the atomic radius due to the increase in the charge
 

Similar threads

  • · Replies 1 ·
Replies
1
Views
3K
Replies
4
Views
2K
  • · Replies 9 ·
Replies
9
Views
5K
Replies
6
Views
6K
Replies
0
Views
2K
  • · Replies 11 ·
Replies
11
Views
7K
Replies
1
Views
1K
  • · Replies 1 ·
Replies
1
Views
14K
  • · Replies 2 ·
Replies
2
Views
7K
Replies
2
Views
2K