Finding the probability of making a measurement E1

Click For Summary

Discussion Overview

The discussion revolves around finding the probability of measuring the energy eigenvalue E1 in the context of quantum mechanics, specifically related to the infinite square well problem as presented in Griffiths' textbook. Participants explore the normalization of wavefunctions, the dependence of amplitudes on quantum numbers, and the formulation of time-dependent solutions.

Discussion Character

  • Technical explanation
  • Debate/contested
  • Mathematical reasoning

Main Points Raised

  • One participant suggests that the amplitude of the wavefunction is independent of n, leading to the conclusion that the probability of measuring E1 is the amplitude squared, which they claim is the same for all energy eigenvalues.
  • Another participant questions the independence of the amplitude on n, noting that typically the amplitude is dependent on n and that the time-dependent solution involves a complex exponential term that is also dependent on n.
  • Some participants clarify that the normalization constant A is not the same as the probability amplitude and emphasize the need to express the wavefunction in the energy eigenbasis to find the probability of measuring E1.
  • There is a discussion about whether to multiply both solutions in different regions by the same exponential time-dependence term and whether the energy states for the wavefunction can be assumed to be the same as for a typical particle in a box.
  • One participant expresses uncertainty about the problem's specification of E and decides to leave it in terms of E1, while another emphasizes the importance of understanding eigenfunctions and the linearity of the Schrödinger equation.
  • Several participants engage in clarifying the process of determining coefficients for the wavefunction in the energy eigenbasis using integrals, specifically mentioning Fourier coefficients.

Areas of Agreement / Disagreement

Participants express differing views on the dependence of the amplitude on n and the correct approach to finding the probability of measuring E1. There is no consensus on the interpretation of the amplitude's independence from n, and the discussion remains unresolved regarding the implications of this independence for the probability calculations.

Contextual Notes

Participants note that the problem does not specify what E is, leading to ambiguity in the discussion. There are also references to the complexity of the mathematics involved and the need for clarity in expressing the wavefunction in terms of energy eigenstates.

Vitani1
Messages
51
Reaction score
9
Summary:: How to solve this?

See attached. This is from Griffiths 3rd edition quantum mechanics textbook, problem 2.7:

This is the solution for an infinite square well. I am to find the probability of obtaining E1 where En = n^2pi^2hbar^2/2ma^2.

E1 = hbar^2pi^2/2ma^2

When finding the amplitude of this wavefunction from normalization you will see that it is independent of n. Therefore the probability of measuring E1 is the amplitude squared which is the same for all energy eigenvalues. Is this correct?

Thanks
 

Attachments

  • Pic.png
    Pic.png
    17.7 KB · Views: 514
Physics news on Phys.org
Vitani1 said:
When finding the amplitude of this wavefunction from normalization you will see that it is independent of n.
You mean ##A## is independent of ##n## ?
Is that the way to find ##\Psi(x, t)## ?
 
Typically the amplitude is dependent on n, but for this example this is not the case? To find psi(x,t) you will add a time-dependent complex exponential term which is dependent on n. To find the probability amplitude isn't it the same for if you squared the time-dependent and time-independent solutions?
 
Of course, it's independent of ##n##. Why should the state depend on ##n##. It's representing the state the particle is prepared in. The question now is, what's the probability to measure the energy eigenvalue ##E_1## when you measure the energy.
 
  • Like
Likes   Reactions: etotheipi
Vitani1 said:
Typically the amplitude is dependent on n, but for this example this is not the case?
The variable ##A## is a normalization constant, not a probability amplitude which is what you seem to be referring to.
 
  • Like
Likes   Reactions: etotheipi
I need to square this probability amplitude A (the coefficient in front of psi) and this is to give me the probability of obtaining the energy eigenvalue. When solving for the particle in an infinite square well there is typically a dependence on n as in Ancos(nx)+Bnsin(nx) = psi(x,0). To obtain the energy eigenvalue E1 you would use the equation Acos(x)+Bsin(x) (for example - this is not the exact solution). For this problem the solution is different since it is not a sum of trigonometric eigenfunctions and this coefficient An (or Bn) is independent of n. Therefore I'm concluding that squaring this amplitude A given in the problem is the correct solution giving the probability of a particle having energy E1 but I'm saying further that this same value is the probability for all energy values E (again due to no n-dependence). Is this correct?
 
Vitani1 said:
I need to square this probability amplitude A (the coefficient in front of psi) and this is to give me the probability of obtaining the energy eigenvalue. When solving for the particle in an infinite square well there is typically a dependence on n as in Ancos(nx)+Bnsin(nx) = psi(x,0). To obtain the energy eigenvalue E1 you would use the equation Acos(x)+Bsin(x) (for example - this is not the exact solution). For this problem the solution is different since it is not a sum of trigonometric eigenfunctions and this coefficient An (or Bn) is independent of n. Therefore I'm concluding that squaring this amplitude A given in the problem is the correct solution giving the probability of a particle having energy E1 but I'm saying further that this same value is the probability for all energy values E (again due to no n-dependence). Is this correct?
No, that's not correct. You need to express the wavefunction you are given in the energy eigenbasis. Or, at least, find the coefficient of ##\psi_1## when expressed in this basis.

Hint: Fourier's trick.
 
  • Like
  • Love
Likes   Reactions: vanhees71 and etotheipi
When you say eigenbasis do you mean express this psi1 in terms of the energy eigenstate? i.e. find the Fourier representation of x and use this? This is what I initially tried to do but this solution is a bit messy.
 
Vitani1 said:
When you say eigenbasis do you mean express this psi1 in terms of the energy eigenstate? i.e. find the Fourier representation of x and use this? This is what I initially tried to do but this solution is a bit messy.
Yes. QM gets messy sometimes.
 
  • #10
This has been completed. I like this solution. I now have the time-independent SE in terms of the Fourier eigenstates. To get the time-dependent equation (hence an equation which is dependent on E) then I just multiply my argument by the exponential term including En. Since this is piecewise do I multiply both top and bottom solutions for both regions by the same exponential time-dependence term including the first term in the second region (which is a constant)? Also would it be okay to assume that the energy states for this wavefunction are the same as for a typical particle in a box?
 
  • #11
Vitani1 said:
When you say eigenbasis do you mean express this psi1 in terms of the energy eigenstate? i.e. find the Fourier representation of x and use this? This is what I initially tried to do but this solution is a bit messy.
Show us what you did. The integral is pretty straightforward.
 
  • Like
Likes   Reactions: Vitani1
  • #12
Vitani1 said:
This has been completed. I like this solution. I now have the time-independent SE in terms of the Fourier eigenstates. To get the time-dependent equation (hence an equation which is dependent on E) then I just multiply my argument by the exponential term including En. Since this is piecewise do I multiply both top and bottom solutions for both regions by the same exponential time-dependence term including the first term in the second region (which is a constant)? Also would it be okay to assume that the energy states for this wavefunction are the same as for a typical particle in a box?
This is where mathematics is clearer than words. The energy eigenstates depend on the system, not on the initial wavefunction.
 
  • Like
Likes   Reactions: Vitani1
  • #13
I would do this but I don't have a way to scan my papers. I have the correct result. I'll try and put it into "better" words. The time-dependent solution can be obtained by multiplying your independent solution by a complex exponential which includes hbar, i, and En. I've written the problem in terms of Fourier basis functions for psi(x,0). Now I would like to multiply both solutions in each region by this exponential to obtain the time-dependent SE. When I do this do I multiply the constant term (the first term in the second region between a/2 and a) by this exponential or just the second term since there exists on this term an explicit n-dependence?
 
  • #14
Actually what you just said helps... this problem doesn't specify what E is so I guess I'll leave this in terms of E1.
 
  • #15
Vitani1 said:
this problem doesn't specify what E is so I guess I'll leave this in terms of E1.
This problem statement has no occurrence of the word or term ##E##.

It seems to me you approximately know what needs to be done, but don't fully grasp the all-important concept of eigenfunctions

You have a ##\Psi(x,0)## given and you know the solutions for the time independent Schrödinger equation ##H\Psi(x) = E\Psi(x)##. The solutions (eigenfunctions of ##H##) have energy ##E_n##, so $$H\Psi_n(x) = E_n\Psi_n(x)\ .$$
You know the time dependence of the eigenfunctions is $$ \Psi_n(x,t) = \Psi_n(x) \,e^{-i\omega_n t} $$ with ##E_n = \hbar \omega_n##.

The Schrödinger equation is linear, so if you can write your given ##\Psi(x,0)## as $$\Psi(x,0)=\sum C_n\Psi_n(x)\ ,$$ then you have $$\Psi(x,t) = C_n\Psi_n(x) \,e^{-i\omega_n t} $$

You determine the ##C_n## from ##\Psi(x,0)## by evaluating the integrals $$\int_{-\infty}^{+\infty} \Psi_n^* \, \Psi(x,0) \; dx\ ,$$which in this exercise means evaluating Fourier coefficients.

Can I ask you to confirm that you understand all this ?
##\ ##
[edit] I notice I used all uppercase ##\Psi##, where Griffith is more clear and uses lower case for the eigenfunctions.
 
Last edited:
  • Like
Likes   Reactions: vanhees71 and Vitani1
  • #16
Yes. I understand.
 
  • #17
Excellent. So, where are we in this exercise ?
  1. ##A## is determined
  2. An expression for ##\Psi(x,t)## is found
  3. The probablility to find ##E_1##
  4. <Energy> of ##\Psi(x,t)##
Vitani1 said:
I would do this but I don't have a way to scan my papers. ##\qquad## Don't bother unless you can do better and neater than a textbook. Exception: the sketch asked for in part (a) of the exercise :wink:

I have the correct result. I'll try and put it into "better" words. ##\qquad##Don't bother -- no one will read the reams of text to comprehesively and unequivocally express even a few equations

The time-dependent solution can be obtained by multiplying your time independent solution by a complex exponential which includes hbar, i, and En. ##\qquad##Correct only for eigenfunctions. For the given initial state (which is a sum of time-independent solutions), this multiplication has to be done term by term (each term has a different ##E_n##).

I've written the problem in terms of Fourier basis functions for psi(x,0). ##\qquad##Not the problem, but the given initial state, I hope :smile: . Do you think you can share the outcome with us (see below) ?

Now I would like to multiply both solutions in each region by this exponential to obtain the time-dependent SE. ##\qquad##Both solutions ? each region ?

When I do this do I multiply the constant term (the first term in the second region between a/2 and a) by this exponential or just the second term since there exists on this term an explicit n-dependence?##\qquad##You have lost me (which is why I posted #15)

Free tip: instead of typing
Vitani1 said:
obtaining E1 where En = n^2pi^2hbar^2/2ma^2.
learn a little bit of ##\ \LaTeX \ ## and type

$$E_n = \frac {n^2\pi^2 \hbar^2} { 2ma^2} $$​
to get $$E_n = \frac {n^2\pi^2 \hbar^2} { 2ma^2} $$Oh boy, what a long post :rolleyes:

##\ ##
 
  • Like
Likes   Reactions: Vitani1
  • #18
This homework is completed. Thank you.
 
  • Like
Likes   Reactions: BvU

Similar threads

  • · Replies 12 ·
Replies
12
Views
5K
  • · Replies 6 ·
Replies
6
Views
2K
  • · Replies 2 ·
Replies
2
Views
1K
  • · Replies 1 ·
Replies
1
Views
2K
  • · Replies 8 ·
Replies
8
Views
2K
  • · Replies 3 ·
Replies
3
Views
2K
  • · Replies 31 ·
2
Replies
31
Views
3K
  • · Replies 2 ·
Replies
2
Views
3K
  • · Replies 10 ·
Replies
10
Views
3K
  • · Replies 77 ·
3
Replies
77
Views
9K