Functions with operator valued arguments acting on eigenstates

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Discussion Overview

The discussion revolves around the application of operator-valued functions on energy eigenstates in quantum mechanics, specifically examining the relationship between these functions and their eigenvalues. The scope includes theoretical aspects of quantum mechanics and the mathematical treatment of operators.

Discussion Character

  • Technical explanation
  • Conceptual clarification
  • Debate/contested

Main Points Raised

  • One participant questions the generality of the relationship between operator-valued functions and energy eigenstates, specifically whether it holds for functions beyond the exponential form, such as sin(H).
  • Another participant explains that functions of operators can be defined through power series, leading to the result that f(H)|E>=f(E)|E> as long as the series converges.
  • A later reply emphasizes that if the operator's eigenvalues exceed the convergence radius of the power series, issues may arise in applying this relationship.

Areas of Agreement / Disagreement

Participants express some agreement on the mathematical framework for operator-valued functions, but there remains uncertainty regarding the applicability of this framework to all functions and the implications of convergence issues.

Contextual Notes

Limitations include the dependence on the convergence of power series and the specific conditions under which the relationship holds. The discussion does not resolve whether all functions satisfy the stated relationship.

Who May Find This Useful

Readers interested in quantum mechanics, operator theory, and the mathematical foundations of quantum states may find this discussion relevant.

qtm912
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This question concerns the outcome when operator valued functions act on an energy eigenstate. Given an eigenstate at t =0, say |Ej > , I have seen or inferred in some of the literature that the following applies :

exp(-iHt/h) |Ej > = exp(- iEj t/h) |Ej >

Where h = h-bar
Ej is energy eigenstate j
H is the Hamiltonian

I am unclear in particular why we can say that if we apply a function with an operator as the argument to this energy eigenstate, it will return the function with the eigenvalue as the argument times the energy eigenstate. (assuming I have inferred what is in the notes correctly)

Would this then be a general result for all functions or do only certain functions satisfy this relationship. (So for example would it be true for sin(H) instead of exp(-iHt/h) )?
 
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Functions of operators are defined from the power series for those functions. So, because H|E>=E|E>, and H^2|E>=H(E|E>)=E(H|E>)=E^2|E>, etc., as long as these power series converge, then you will have f(H)|E>=f(E)|E>.
 
Thank you matterwave for the clear explanation
 
Matterwave said:
Functions of operators are defined from the power series for those functions. So, because H|E>=E|E>, and H^2|E>=H(E|E>)=E(H|E>)=E^2|E>, etc., as long as these power series converge, then you will have f(H)|E>=f(E)|E>.

Thus, if the operator has eigenvalues that exceed the convergence radius of the expansion, problems will arise.
 
Yes, makes sense, thanks for pointing it out torquil.
 

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