Do you mean like using degrees on the x-axis instead of radians? So the period of the sine function would be 360 and all the angles you mention above are nice whole numbers like 90, 180, and 270.
The answer is yes, we could do that. But if you think dealing with pi as you have mentioned above is a nuisance now, it is nothing compared with the nuisance you would encounter in calculus if you use degrees. The derivatives of sine and cosine functions work out the simplest when their argument is measured in radians. If you use degrees, all the formulas would have a nuisance factor compensating for that awkward choice. It is a similar situation that causes the natural logarithms (base e) to be the easiest to work with. If you haven't had calculus yet, you will have to wait to understand this, but you will see then.