An atom isn’t a little round ball so we want to be cautious about using words like “size” - there’s a notion of atomic size but it’s not quite like what we mean when we talk about the size of a billiard ball.
Whether a photon is absorbed or scattered by an atom depends on how it interacts with the individual charged particles that make up the atom, and these are close to (in the case of the electron exactly, as far as we know) point particles. So the answer to your question is somewhere between “that’s not a good way of thinking about it” and “no”.