Halogenation of an alcohol (iodation)

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duchuy
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Homework Statement
Turn R-OH to R-I
Relevant Equations
x
I don't understand why in order to make RI from ROH, you'd have to use FINSKELSTEIN condition:
ROH + PBR3 --> RBr
RBr + NaI --> RI + NaBr

and not directly
ROH + PI3 --> RI

Thank you so much for your help!
Pardon me if my english is not correct.

<mentor edit>
 
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