Finding Hydration & Solubility of LiI: Endo/Exo?

  • Thread starter Thread starter Apostle
  • Start date Start date
  • Tags Tags
    Heat
Click For Summary
SUMMARY

The heat of hydration for lithium iodide (LiI) when dissolved in water is exothermic, resulting in a negative delta H value, indicating energy is released. Conversely, the heat of solution is endothermic, requiring energy input to dissociate LiI into its constituent ions, resulting in a positive delta H value. To determine these values, one can either conduct experimental measurements or reference established data from scientific tables.

PREREQUISITES
  • Understanding of thermodynamics, specifically enthalpy changes.
  • Familiarity with the concepts of exothermic and endothermic reactions.
  • Knowledge of ionic compounds and their behavior in aqueous solutions.
  • Ability to interpret thermodynamic tables for heat of hydration and heat of solution values.
NEXT STEPS
  • Research the experimental methods for measuring heat of hydration and heat of solution.
  • Study thermodynamic tables for standard enthalpy values related to LiI.
  • Learn about the Born-Haber cycle and its application to ionic compounds.
  • Explore the principles of calorimetry for practical applications in measuring heat changes.
USEFUL FOR

Chemistry students, particularly those in introductory courses, educators teaching thermodynamics, and researchers interested in ionic compound solubility and hydration energy.

Apostle
Messages
1
Reaction score
0
Heat of Hydration?

My text asks me to find the (delta H hydration = ? kj/mol ) and
the (delta Hsoln =? kj/mol) when LiI (lithium iodide) is dissolved in water and the solution becomes hotter. Endo/Exo?? And how do I find the kj/mol's. I am a first year student and starting in the middle of the year, so I am a little behind so to speak.
Sorry about any wrong info. This is my first time on this site.:cry:
 
Physics news on Phys.org
Heat of hydration is the energy given out when the Li and I bond with water - This will be pretty exothermic ( energy given out = negative )
Heat of solution is the energy needed to break the LiI into separate ions, this takes energy and is endothermic ( energy taken in = positive )

Be careful though - you could also define the heat of solution to be the total energy generated ie heat hydration + heat solution.
I don't know how you work these out from first principles, you would eithe rmeasure it in an experiment or use values from tables (of other people experiments )
 

Similar threads

  • · Replies 3 ·
Replies
3
Views
3K
  • · Replies 5 ·
Replies
5
Views
5K
  • · Replies 10 ·
Replies
10
Views
6K
  • · Replies 39 ·
2
Replies
39
Views
6K
  • · Replies 1 ·
Replies
1
Views
4K