A Hermitian operator is defined as an operator in quantum mechanics where the diagonal elements of its matrix representation are real, and the off-diagonal elements are complex conjugates of each other. This property ensures that the Hermitian conjugate of the operator equals itself, making it crucial for representing measurable quantities in quantum mechanics. The eigenvalues of Hermitian operators are always real numbers, which corresponds to the outcomes of measurements. For instance, measuring the z-directed spin of an electron in a specific state yields a definite result, demonstrating the operator's role in the measurement process. Understanding Hermitian operators is essential for grasping the fundamentals of quantum mechanics.