High speed polymerization reaction initiated by the action

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SUMMARY

The discussion focuses on a high-speed polymerization reaction initiated by laser light, specifically monitoring unreacted acrylate double bonds using Fourier Transform Infrared (FTIR) spectroscopy. The acrylate double bond, characterized by the bond between CH2 and CH, absorbs infrared radiation, with the carbonyl peak shifting when conjugated to the double bond. FTIR is preferred over other spectroscopic techniques due to its rapid scanning capability, allowing for scans in less than a second compared to several minutes for traditional scanning IR methods.

PREREQUISITES
  • Understanding of acrylate chemistry and double bonds
  • Familiarity with Fourier Transform Infrared (FTIR) spectroscopy
  • Knowledge of polymerization processes
  • Basic principles of infrared radiation absorption
NEXT STEPS
  • Research the principles of Fourier Transform Infrared (FTIR) spectroscopy
  • Study the mechanisms of high-speed polymerization reactions
  • Explore the significance of acrylate double bonds in polymer chemistry
  • Investigate the differences between FTIR and traditional scanning IR spectroscopy
USEFUL FOR

Chemists, materials scientists, and researchers involved in polymerization processes and spectroscopic analysis will benefit from this discussion.

EIRE2003
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So what's happening is a high speed polymerization reaction initiated by the action of laser light.

An infrared beam moniters the amount of unreacted acrylate double bonds. But what is an acrylate double bond? Am I correct in saying that a double bond absorbs IR radiation?
The double bond is the bond between a CH2 and a CH, in the paper that I am reading.

My next question is, why use Fourier Transform Infrared spectroscopy over any other spectroscopic technique to determine the amount of unreacted double bonds through time in a sample?
 
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EIRE2003 said:
So what's happening is a high speed polymerization reaction initiated by the action of laser light.

An infrared beam moniters the amount of unreacted acrylate double bonds. But what is an acrylate double bond? Am I correct in saying that a double bond absorbs IR radiation?
That's the one.

The double bond is the bond between a CH2 and a CH, in the paper that I am reading.
Actually the double bond conjugated to the carbonyl is the absorbing species. The carbonyl peak shifts slightly when conjugated to the double bond.

My next question is, why use Fourier Transform Infrared spectroscopy over any other spectroscopic technique to determine the amount of unreacted double bonds through time in a sample?
You can take a FT scan in less than a second vs a scanning IR that might take a few minutes per scan.
 


Thank you :)
 

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