There are at least three known mechanisms for nuclear fusion.
Stars with mass comparable to that of the sun rely almost completely on the proton-proton chain. This requires temperatures of about 15 million kelvins. From a classical point of view, even such temperatures would not be sufficient to overcome the coulomb potential between protons in the stellar plasma. Only quantum mechanics, and in particular so called tunnel effect, fully accounts for the entire process. Also electroweak forces intervene: they are responsible for the process that takes a proton into a neutron and an electric neutrino. This stage produces deuterium; deuterium can then fuse to produce helium-3 particles and finally, alpha-particles.
For stars with about 10 solar masses, carbon cycle is the dominant mechanism.
For even more massive stars (red giants and supergiants) with temperature above 100 million kelvins, helium can fuse directly to form beryllium and then carbon (triple alpha process).
With still more massive and older star, hydrogen fuel begins to run out. Neon and oxygen burning take place. Then, the star approaches the peak of the binding curve, the so called iron peak: when iron is produced the star is doomed, since this process is endothermic and so takes energy from the outside: the star will collapse and finally explode in a type II supernova. A very brief phase before this moment is the so called silicon burning process: here massive stars can reach temperatures of even 3.5 billions K!