How Are Electrons Distributed Among Px, Py, and Pz Orbitals in Carbon?

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SUMMARY

The distribution of electrons among the px, py, and pz orbitals in carbon is determined by Hund's rule and the concept of pairing energy. Carbon has an electron configuration of 1s² 2s² 2p², meaning it has four electrons in the second shell, with two in the s orbital and two in the p orbitals. Since the px, py, and pz orbitals are degenerate (having the same energy), the two p electrons will occupy separate orbitals to minimize repulsion, as per Hund's rule. The specific distribution can vary based on the element and its unique pairing energy requirements.

PREREQUISITES
  • Understanding of atomic orbitals and electron configurations
  • Familiarity with Hund's rule and the Pauli exclusion principle
  • Knowledge of pairing energy and its implications in electron distribution
  • Basic concepts of quantum mechanics related to electron behavior
NEXT STEPS
  • Research the implications of Hund's rule in multi-electron atoms
  • Explore the concept of pairing energy in different elements
  • Study the quantum mechanical model of atomic orbitals
  • Learn about the effects of electron-electron interactions in atomic structure
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Chemistry students, educators, and anyone interested in atomic structure and electron distribution in elements, particularly in understanding the behavior of p orbitals in carbon and other elements.

zachnorious
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Hello I didn't get something about the AO.

i.e the electron configuration of C is 1s² 2s² 2p² . So we know that at the 2nd shell this has 4 electrons, 2 in s orbital + 2 in the p, right?
How do we find out how the 2 electrons of p are spread in the px, py, pz?

Thank you,
Panos
 
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I mean since px,py,pz have the same energy is there any other rule that tell us how many electrons are in each p (px,py,pz) or is this different from element to element and each one has a characteristic px,py,pz for no specific reason?
 
Last edited:
Those suborbitals are of equal energy (x,y,z). Name them any way you want. They are all identical except that they are mutually orthogonal (in this case). Have you heard of pairing energy. How much extra energy does it take to unpair the electrons thereby allowing them to occupy different suborbitals?
 

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