How are the excitation energies of helium determined experimentally?

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SUMMARY

The excitation energies of the helium atom are determined experimentally through photon emission during electron transitions between orbitals. Specifically, the transition from the 1s to the 2p orbital requires 21 eV, which corresponds to ultraviolet photons that are not visible. The visible excitation energies are approximately 2.5 eV, corresponding to photon wavelengths around 500 nm, indicating these transitions occur from higher energy levels such as 2s and above. Comprehensive data on helium's energy levels can be found in the NIST Physics Reference Data.

PREREQUISITES
  • Understanding of atomic orbitals and electron transitions
  • Familiarity with photon energy calculations and the relationship between energy and wavelength
  • Knowledge of ionization energy versus excitation energy
  • Basic grasp of spectroscopy and visible light spectrum
NEXT STEPS
  • Research the concept of photon emission in atomic transitions
  • Study the NIST Physics Reference Data for detailed helium energy levels
  • Learn about the differences between ionization energy and excitation energy
  • Explore the principles of spectroscopy and how it relates to atomic energy levels
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Students and researchers in physics, particularly those focusing on atomic structure, spectroscopy, and quantum mechanics, will benefit from this discussion.

pivoxa15
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What is the excitation energy of the He atom?

I imagine this is also the energy of the photon released by the electron as it deexcites from the p orbital to the s orbital.

I guess this would be different to ionisation energy as that refers to taking the electron away completely from the atom.

Is it explained here with 9 different excitation levels?
http://hyperphysics.phy-astr.gsu.edu/hbase/quantum/atspect.html

It looks like going from 1s to 2p recquires 21eV. But from this graph
http://hyperphysics.phy-astr.gsu.edu/hbase/quantum/atspect.html
it looks like the excitation energies are around 2.5eV corresponging to around 500nm wavelength photons. Is that because they only showed excitations not from 1s but from 2s and above? In fact the excitation from 1s would recquire 21eV or more corresponding to a photon of wavelength in the ultaviolet range so can't be seen. The site lists ones that can be seen so can't be the 21eV photons.
 
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