How can i calculate the solbilty of silver chloride?

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SUMMARY

The solubility of silver chloride (AgCl) can be calculated using its solubility product constant (Ksp), which is 1.8x10-10 mol2dm-6 at room temperature (RTP). To find the solubility in pure water, the equation Ksp = [Ag+] x [Cl-] is applied, leading to S = √(1.8x10-10). The conversion from moles to grams per cubic decimeter (g dm-3) requires knowledge of the molar mass of AgCl. Additionally, silver chloride is less soluble in a silver nitrate solution due to the common ion effect, and it is more soluble in aqueous ammonia due to the formation of soluble complexes.

PREREQUISITES
  • Understanding of solubility product constant (Ksp)
  • Knowledge of molar mass calculations
  • Familiarity with the common ion effect
  • Basic principles of complex ion formation in aqueous solutions
NEXT STEPS
  • Research the calculation of solubility from Ksp values
  • Learn about the common ion effect and its implications on solubility
  • Study the formation of complex ions in solutions, specifically with ammonia
  • Explore the molar mass of silver chloride (AgCl) for conversion purposes
USEFUL FOR

Chemistry students, educators, and professionals involved in analytical chemistry or solubility studies, particularly those focusing on ionic compounds and their behavior in various solutions.

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Homework Statement



Ksp of silver chloride is 1.8x10-10 mol2dm-6 at RTP

a) calculate the solubility of silver chloride in gdm-3 in
i) pure water
ii) in 0.1M silver nitrate solution

b)Is silver chloride more soluble in water of in a solution containing silver ions. Why?
c) Why is silver chloride more soluble in aquouse ammonia than in water?


Homework Equations



AgCl = Ag+ x Cl-


The Attempt at a Solution



Ksp = [Ag+] x [Cl-]
1.8x10-10 = S x S

S= √1.8x10-10

Which i find the solubility. How do i convert it to g dm-3?

b)?
c)?
 
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What units will your solubility be in?

Before answering b try to solve a ii. c refers to additional reaction that takes place in the ammonia solution.
 
mol/dm3
 
Well, you know how many moles of AgCl dissolve in a liter of water. Just convert from moles of AgCl to grams of AgCl and realize that a liter is the same volume as a cubic decimeter.
 

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