How can the acidity constant of water in itself be defined?

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SUMMARY

The acidity constant of water, denoted as Ka(H2O), can be defined through the equilibrium reaction H2O + H2O ↔ H3O+ + OH-. The derived formula is Ka(H2O) = [H3O+]⋅[OH-] / [H2O], leading to the conclusion that Ka(H2O) equals Kw/[H2O], which results in a value of 10^-15.7. However, the discussion raises a critical point regarding the assumption of water being in a "dilute solution," questioning the validity of this assumption for water dissociation. The activity of water is considered to be equal to 1, suggesting that Ka(H2O) should align with Kw = 10^-14 instead.

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Sorry if this question has already been asked but I didn't find it in this forum.

Which is the acidity constant of water in itself?

Ka of a weak acid HA in water dilute solution is defined considering the aequilibrium:

HA + H2O ↔ H3O+ + A- (1)
then:
Ka(HA) = [H3O+]⋅[A-] / [HA]

this, for what I know, because in dilute solution [H2O] is constant and can then be "incorporated" in the aequilibrium constant Keq:

Keq. = [H3O+]⋅[A-] / [HA]⋅[H2O]

Ka = Keq⋅[H2O] = constant1⋅constant2.

So, my "natural" guess to how Ka(H2O) can be defined, would be to replace HA with H2O in the aequilibrium (1) and then as follow.
Let's consider the aequilibrium:

H2O + H2O ↔ H3O+ + OH-

then:

Ka(H2O) = [H3O+]⋅[OH-] / [H2O] = Kw/[H2O] = 10-14/(1000/18) = 10-15.7.

But there is a problem: can I here really consider the acid H2O as in "dilute solution"? It seems meaningless...

How would you define the acidity constant of water in itself, in case is definible?

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"Dilute solution" in this context typically means "water concentration can be assumed to be constant".

Does it hold for water dissociation? (Hint: compare concentration of dissociation products with concentration of water itself).
 
Borek said:
"Dilute solution" in this context typically means "water concentration can be assumed to be constant".

Does it hold for water dissociation? (Hint: compare concentration of dissociation products with concentration of water itself).
From your answer I deduce that my definition of Ka(H2O) is correct. Is it?
Now let's see it from the point of view of activities.
Concerning [H3O+]and [OH_] there is no problem because they are so small to be certainly equal to their activities. But the activity of water is (or it should be) equal to 1. Is it correct?
But then Ka(H2O) should be equal to Kw = 10-14 and not 10-15.7.

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