How do you apply perturbation theory to a magnetic field Hamiltonian?

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SUMMARY

The discussion focuses on applying perturbation theory to the spin Hamiltonian of a spin-1/2 particle in an external magnetic field defined as \( \hat{H} = -\frac{gq}{2mc} \hat{S} \cdot B \) with \( B = B_0 \hat{k} + B_2 \hat{j} \) and \( B_2 \ll B_0 \). The user attempts first- and second-order perturbation calculations but encounters discrepancies, particularly in evaluating expectation values of spin operators and deriving exact energy eigenvalues. The exact solution involves diagonalizing the Hamiltonian matrix using Pauli matrices, yielding eigenvalues \( \lambda = \pm \hbar \omega_0 \sqrt{B_0^2 + B_2^2} \). The teaching assistant clarifies that the first-order correction should be zero due to orthogonality and that the exact eigenvalues expand as \( \pm \hbar \omega_0 \left[1 + \frac{1}{2}\left(\frac{B_2}{B_0}\right)^2 + \ldots \right] \), consistent with perturbation theory results through second order in \( \frac{B_2}{B_0} \).

PREREQUISITES

  • Quantum Mechanics perturbation theory (first and second order)
  • Spin-1/2 systems and spin operator algebra
  • Pauli matrices and their matrix representations
  • Diagonalization of 2x2 Hermitian matrices

NEXT STEPS

  • Study exact diagonalization techniques for spin Hamiltonians using Pauli matrices
  • Review perturbation theory expansions for degenerate and non-degenerate systems
  • Analyze expectation values of spin operators in eigenstates of \( \hat{S}_z \) and \( \hat{S}_y \)
  • Explore time-dependent perturbation theory for spin dynamics under oscillating magnetic fields

USEFUL FOR

Physics students and researchers working on quantum spin systems, particularly those applying perturbation theory to magnetic Hamiltonians. This discussion benefits anyone needing to reconcile exact diagonalization results with perturbative approxim

Danielk010
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TL;DR
Given,
Take with . Determine the energy eigenvalues exactly and
compare with the results of perturbation theory through second order in .
I understand that the first order results would be ##\langle \phi_n^0 | -\mu * B | \phi_n^0 \rangle## = ##\langle \phi_n^0 | -\frac{gq}{2mc}\hat{S} * B | \phi_n^0 \rangle##, the second order results would be ##\sum_{k \ne n} \frac{|\langle \phi_n^0 | -\mu * B | \phi_n^0 \rangle|^2} {E_n^{(0)} - E_k^{(0)}} ##, and the unperturbed hamiltonian would ##E_n^{(0)} = (n + \frac{1}{2})\hbar\omega##.

I am confused on how to evaluate braket of phi as the problem is asking for the exact energy eigenvalues. I tried plugging in ##B = \frac{-Zev \times r}{cr^3} ##, but then I would have the Z, v and r term, which would not give me an exact solution.


Am I on the right track? Is there an equation I am missing? Thank you for any help on this problem. Also do any of you all know how to add equations to the TL;DR?
 
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Danielk010 said:
TL;DR: Given,
Take with . Determine the energy eigenvalues exactly and
compare with the results of perturbation theory through second order in .
Can you edit your post to very clearly state the problem you are trying to solve?
 
Sorry, I tried to insert LaTeX in the TL;DR but it did not display correctly. I am also past the time limit to edit a post.

Here is the problem:
The spin Hamiltonian for a spin-1/2 particle in an external magnetic field is
$$\hat{H} = -\hat{\mu} * B = - \frac{gq}{2mc}\hat{S} * B$$
Take ##B = B_0k + B_2j\text{, with }B_2 \ll B_0##. Determine the energy eigenvalues exactly and compare with the results of perturbation theory through second ordder in ##\frac{B_2}{B_0}##


I made some progress and I asked the TA for my class for help on this problem. For my initial attempt for the first order differential, I did this:

In the end, I got ##\frac{\omega_0 \hbar}{2} sin w_0t## where ##\omega_1 = -\frac{gq}{2mc}(B_0 + B_2)##.
I started by setting the hamiltonian to be: ## \textbf{Equation 1} = H = -\frac{gq}{2mc} * \hat{S_z}B_0 + \hat{S_y}B_2##.

Assuming, ##\omega_0 = -\frac{gq}{2mc}##, we can set the energy to ##E_n^1 = \omega_0(<n|\hat{S_z}B_0|n> + <n|\hat{S_yB_1}|n>)## given the first-order P.T equation.

Since ##B_0## and ##B_2## are constants, you can get ##w_1(<S_z> + <S_y>)##. From equations (4.23 ##<S_z> = 0##) and (4.30 ##<S_y> = \frac{hbar}{2}sin\omega_0t##)

I get ##E_n^1 = \frac{\omega_0 \hbar}{2} sin w_0t##. According to the TA, it should be 0, which I am confused on how they got that.

For the exact energy eigenvalues, he mentioned to use the Pauli matrices.
I used Equation 1 and by plugging in the Pauli matrices, I got ##
\begin{pmatrix}
\omega_0 B_0 & -i\omega_0 B_2 \\
i\omega_0 B_2 & -\omega_0 B_0
\end{pmatrix}##. By taking the det. I got ##-B_0^2\omega_0^2 + \lambda^2 - B_2^2\omega_0^2## => ##\lambda = \omega_0 \sqrt{B_0^2 + B_2^2} ##. According to the TA, it is supposed to be ##\pm \hbar \omega [1 + ...]##, which is not what I got.

Sorry for the lengthy post, but what did I do wrong? I am using the A Modem Approach to Quantum Mechanics Second Edition textbook. Please let me know if there is anything else I need to provide.
 
Last edited:

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