How is Gibbs Free Energy Calculated?

  • Thread starter Thread starter afcwestwarrior
  • Start date Start date
  • Tags Tags
    Delta
Click For Summary
SUMMARY

The calculation of Gibbs Free Energy (ΔG) can be performed using two primary methods: ΔG = ΔH – T * ΔS and ΔG = G_products – G_reactants. The first method is universally applicable at any specified temperature, while the second is only valid at the temperature for which the Gibbs values are calculated. For non-spontaneous reactions, determining the temperature required for spontaneity necessitates using the ΔG = ΔH – T * ΔS formula, as it provides a more comprehensive approach to Gibbs Free Energy calculations.

PREREQUISITES
  • Understanding of thermodynamic concepts such as enthalpy (H) and entropy (S).
  • Familiarity with the Gibbs Free Energy equation and its components.
  • Knowledge of standard conditions in thermodynamics.
  • Ability to interpret thermodynamic tables, specifically Gibbs free energy of formation values.
NEXT STEPS
  • Study the derivation and applications of the Gibbs Free Energy equation.
  • Learn how to use thermodynamic tables for calculating Gibbs Free Energy under standard conditions.
  • Research methods for determining temperature adjustments for non-spontaneous reactions.
  • Explore the relationship between Gibbs Free Energy and chemical equilibrium.
USEFUL FOR

Chemistry students, researchers in thermodynamics, and professionals involved in chemical engineering or reaction kinetics will benefit from this discussion.

afcwestwarrior
Messages
453
Reaction score
0
do i have to use this formula Delta G=delta h- t*delta s

or could i calculate it like i calculate delta h, products - reactants
 
Chemistry news on Phys.org
I think you can do either way. Which way is depending on what data you've got in hand
 
Calculating the change in the Gibbs Free Energy as,
ΔG = ΔH – T * ΔS
Is a more general way to do it since this will be true for any specified temperature, T.

You could calculate it as,
ΔG = G_products – G_reactants
But this will only be valid for the temperature which your table has its G values calculated in. You might have access to a table of standard G of formation, but this would only be true under standard conditions.
What if you had a non-spontaneous reaction (under standard conditions) and you wanted to find out the temperature you needed to raise it to in order to make it spontaneous? To do this, you would have to calculate it the old fashion way without the Free Energy table.
 
Gibbs free energy equation is a thermodynamic equation that is used to calculate the change in the Gibbs free energy of a system. The Gibbs Free Energy equation is written as G=H-TS Where G is the Gibbs Free Energy, H is the enthalpy, T is the absolute temperature and S is the entropy.
 

Similar threads

Replies
3
Views
2K
  • · Replies 4 ·
Replies
4
Views
3K
  • · Replies 11 ·
Replies
11
Views
3K
Replies
7
Views
2K
  • · Replies 4 ·
Replies
4
Views
2K
  • · Replies 1 ·
Replies
1
Views
2K
  • · Replies 2 ·
Replies
2
Views
2K
  • · Replies 2 ·
Replies
2
Views
2K
Replies
12
Views
3K
  • · Replies 81 ·
3
Replies
81
Views
9K