How do you know what salt to use for salt bridge?

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SUMMARY

The selection of salts for a salt bridge in electrochemical cells is crucial to prevent unwanted reactions while maintaining ionic balance. The primary function of the salt bridge is to neutralize the solution, preventing the buildup of anions or cations that could halt cell operation. Ideal salts are those that do not react with the components of the cell, and their selection often involves comparing reduction potentials to ensure minimal interference. Artful selection of salts can yield effective results, although challenges arise in cells with transport mechanisms.

PREREQUISITES
  • Understanding of electrochemical cells and their components
  • Knowledge of ionic compounds and their properties
  • Familiarity with reduction potentials and their significance
  • Basic principles of chemical reactivity and inert substances
NEXT STEPS
  • Research specific salts commonly used in salt bridges, such as KCl and NaNO3
  • Study the concept of reduction potentials and how they influence salt selection
  • Explore the effects of different ions on electrochemical cell performance
  • Investigate alternative methods for maintaining ionic balance in electrochemical cells
USEFUL FOR

Chemistry students, electrochemists, and anyone involved in designing or studying electrochemical cells will benefit from this discussion.

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Homework Statement


its not a homework question but I didn't know where else to ask.
I want to know how we know which salt to use for salt bridge. I think I understand what we don't want the salt bridge to do --we don't want it to react, and that its function is to neutralize the solution so anions or cations don't build up and the cell stops working. So salt bridge replenishes the ions, right?
But how do we know which salt won't react? Is it a matter of comparing reduction potentials?
thanks for any help!

Homework Equations

The Attempt at a Solution

 
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ppppparker said:
don't want it to react
... and, that said, things turn into a "crap-shoot." "Everything" reacts (or is totally inert). "Artful" selection yields "minimal" effects. Cells "with transport" are more difficult in which to accomplish this goal.
 

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