How is Hamiltonian energy of orbital differ from orbital in certain

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SUMMARY

The Hamiltonian energy of orbitals in different atoms, such as lithium and hydrogen, varies due to differences in atomic number. Although both atoms have one electron in their outer orbital, their distinct atomic numbers result in different potential energy values in the Schrödinger equation. This discrepancy leads to unique Hamiltonian eigenstates and energy levels for each atom. Understanding these differences is crucial for grasping quantum mechanics and atomic structure.

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how is Hamiltonian energy of orbital differ from orbital in certain atom with another atom although the two orbital have the same no. of electrons...
ex...Hamiltonian energy differ in lithium and hydrogen although both have one electron in last orbital
please help me quickly
 
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lol, just curious, why the rush? ;]

Well these 2 atoms you mention have nothing in common. They have different atomic number, which means the potential V (that gets in Schrödinger equation) is different which finally means that you'll get different Hamiltonian eigenstates (energies)
 


r u trust in this answer...and how the atomic no. can change in V
 

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