How Is pV = 1/3 Nmc^2 Derived in Kinetic Theory?

[etotheipi]

Homework Statement

Question regarding derivation of pV = 1/3 Nmc^2

Relevant Equations

$$\Delta t = 2L/v_{x}$$

This is such a small point but I just wondered if anyone could clarify.

It is easy to work out the time between successive collisions with one wall of the box, namely $$\Delta t = 2L/v_{x}$$However, if this time interval is for instance 1 second, then we could have either 1 or 2 collisions in this time interval depending on whereabouts the particle starts (i.e. could be at t=0 and t=1). These would result in different values for exerted force, but evidently this only is a problem at the beginning and end since double counting is definitely wrong.My thinking was that when taking an average over a larger period of time - suppose n time intervals - the total time becomes n\Delta t and if n becomes fairly large the calculated time interval for each collision \frac{n\Delta t}{n} or \frac{n\Delta t}{n+1} approach each other, so it doesn't matter if we count the first/last collisions.

Am I overcomplicating this?

 

[PeroK]

Homework Statement: Question regarding derivation of pV = 1/3 Nmc^2
Homework Equations: $$\Delta t = 2L/v_{x}$$

This is such a small point but I just wondered if anyone could clarify.

It is easy to work out the time between successive collisions with one wall of the box, namely $$\Delta t = 2L/v_{x}$$However, if this time interval is for instance 1 second, then we could have either 1 or 2 collisions in this time interval depending on whereabouts the particle starts (i.e. could be at t=0 and t=1). These obviously result in different values for exerted force.My thinking was that when taking an average over a larger period of time - suppose n time intervals - the total time becomes n\Delta t and if n becomes fairly large the calculated time interval for each collision \frac{n\Delta t}{n} or \frac{n\Delta t}{n+1} approach each other, so it doesn't matter if we count the first/last collisions.

Am I overcomplicating this?

That's one argument. Another is that if the particles are randomly distributed at $t=0$, then the time to the first collision averages out. In any case, it's the large numbers that support a statistical approach.

 

[etotheipi]

That's one argument. Another is that if the particles are randomly distributed at $t=0$, then the time to the first collision averages out. In any case, it's the large numbers that support a statistical approach.

Ahh I hadn't thought of that, that's quite a nice way of thinking of it.