How is the Number of Quantum States Derived for Combined Einstein Solids?

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SUMMARY

The number of quantum states for two combined Einstein solids is derived using the formula g(n,N) = ∑(n_A=0 to n) g(N_A,n_A)g(N_B,n-n_A), where n is the principal quantum number of the composite solid. This formula accounts for the exchange of energy between the two systems, represented by N_A and N_B oscillators. The derivation emphasizes the necessity of summing over all possible discrete energy arrangements when the solids are in thermal contact, allowing for new configurations such as n_A = 3 and n_B = 4 leading to n_{A,NEW} = 0 and n_{B,NEW} = 7.

PREREQUISITES
  • Understanding of Einstein solids and their oscillators
  • Familiarity with quantum states and energy quantization
  • Knowledge of statistical mechanics principles
  • Basic grasp of combinatorial mathematics
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  • Explore the derivation of the partition function in statistical mechanics
  • Study the implications of thermal contact in thermodynamic systems
  • Learn about the concept of microstates and macrostates in quantum mechanics
  • Investigate the role of energy exchange in multi-system interactions
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Physicists, students of quantum mechanics, and researchers in statistical mechanics will benefit from this discussion, particularly those interested in the thermodynamic properties of combined systems.

loonychune
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Two Einstein solids are joined so that they can exchange energy. One contains N_A oscillators, the other N_B oscillators. Apparently, the possible number of quantum states of the combined system is given by,

g(n,N) = \sum_{n_A = 0}^n g(N_A,n_A)g(N_B,n-n_A)

where n is the principal quantum number of the composite solid

n = n_A + n_B

Now, I cannot see where this comes from. I hope this formula looks familiar more than anything, though I will look to write up everything I see here contained in the notes if necessary. Can anyone help?

Thanks,


Damian
 
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Actually, I see it now.

Bringing the two systems into thermal contact means they can exchange energy, so we have to sum over all the possible discrete energies.

e.g.

n_A = 3, n_B = 4 \rightarrow n_{A,NEW} = 0, n_{B,NEW} = 7

is a new possible arrangement.
 

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