How many peaks will there be in an NMR spectrum for Malic Acid?

In summary, there will be a total of 4 peaks in the NMR spectrum of Malic Acid without D2O as the solvent. This is due to the two identical -COOH groups and the three different hydrogen environments within the molecule. The doublets and triplets will be counted as one peak each.
  • #1
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1. Homework Statement

How many peaks will there be in the NMR spectrum of Malic Acid, HOOC CH2 CH(OH) COOH, WITHOUT D2O as the solvent (i.e. Hydrogens in Hydroxyl groups WILL have corresponding peaks)?


3. The Attempt at a Solution

I thought the two -COOH groups will be identical Hydrogen environments, so there would only be one peak for both. There will be one environment with the single H bonded to the Carbon that is also bonded to the OH; one environment with the single H in the -OH bonded to that same Carbon; and one environment with the two H's bonded to the remaining Carbon. A total of 4 peaks without D2O (or 5 if the Carboxylic acid groups are not identical)?
 
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  • #2
Do you count doublets as one peak or two? Triplets as one peak or three?
 
  • #3
Triplets as one, doublets as one
 

1. How does the number of peaks in an NMR spectrum for Malic Acid relate to its structure?

The number of peaks in an NMR spectrum for Malic Acid is directly related to its molecular structure. Each unique chemical environment within the molecule will produce a distinct peak in the spectrum.

2. What is the chemical shift range for Malic Acid in an NMR spectrum?

The chemical shift range for Malic Acid in an NMR spectrum is typically between 1-4 ppm. However, this can vary depending on the instrument used and the solvent used for the sample.

3. How many peaks are expected in the NMR spectrum for Malic Acid?

There are typically six peaks expected in the NMR spectrum for Malic Acid. This is due to the presence of three unique chemical environments within the molecule, each producing two peaks (one for the alpha and beta protons).

4. Can the number of peaks in an NMR spectrum for Malic Acid change under different conditions?

Yes, the number of peaks in an NMR spectrum for Malic Acid can change under different conditions such as pH or temperature. This is because these changes can affect the molecular structure and thus alter the chemical environments within the molecule.

5. What is the significance of the number of peaks in an NMR spectrum for Malic Acid?

The number of peaks in an NMR spectrum for Malic Acid is significant because it provides information about the molecular structure of the compound. By analyzing the number and position of the peaks, scientists can determine the types of chemical bonds and functional groups present in the molecule.

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